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Kinetics of hydrolysis of o-aminomethylphenols and their ammonium salts

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A kinetic study has been made of the hydrolysis of a number of o-aminomethylphenols and their iodomethylates at various levels of pH of the medium. The reaction proceeds through the zwitterion and anionic forms by an elimination-addition mechanism, leading to the formation of o-hydroxybenzyl alcohol.

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Literature cited

  1. P. D. Gardner, H. S. Rafsajani, and L. Rand, J. Am. Chem. Soc.,81, 3364 (1959).

    Google Scholar 

  2. S. V. Cavit, H. R. Sarrafizaden, and P. D. Gardner, J. Org. Chem.,27, 1121 (1962).

    Google Scholar 

  3. F. Troxler, Helv. Chim. Acta,51, 1214 (1968).

    Google Scholar 

  4. R. Andrisano, C. Delia Casa, and M. Tramontini, J. Chem. Soc. C, 1866 (1970).

    Google Scholar 

  5. B. E. Ivanov and L. A. Khismatullina, Izv. Akad. Nauk SSSR, Ser. Khim., 2650 (1968).

  6. B. E. Ivanov, L. A. Valitova, and T. G. Vavilova, Izv. Akad. Nauk SSSR, Ser. Khim., 768 (1968).

  7. S. Yukitani, K. Mamoru, and N. Kenji, J. Chem. Soc. Jpn., Chem. Ind. Chem., 1123 (1978).

  8. J. H. Burchalter, J. Am. Chem. Soc.,68, 1894 (1946).

    Google Scholar 

  9. B. Reichert, Die Mannich Reaction, Springer-Verlag, Berlin (1959).

    Google Scholar 

  10. A. B. Teitel'baum, K. A. Derstuganova, N. A. Shishkina, L. A. Kudryavtseva, V. E. Bel'skii, and B. E. Ivanov, Izv. Akad. Nauk SSSR, Ser. Khim., 803 (1980).

  11. C. McIntosh and O. L. Champan, J. Chem. Soc., Chem. Commun., 71 (1971).

  12. A. B. Teitel'baum, A. M. Kurguzova, L. A. Kudryavtseva, V. E. Bel'skii, and B. E. Ivanov, Izv. Akad. Nauk SSSR, Ser. Khim., 531 (1981).

  13. N. A. Shishkina, K. A. Derstuganova, L. A. Kudryavtseva, V. E. Bel'skii, and B. E. Ivanov, Izv. Akad. Nauk SSSR, Ser. Khim., 1259 (1976).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 81–85, January, 1982.

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Teitel'baum, A.B., Kudryavtseva, L.A., Bel'skii, V.E. et al. Kinetics of hydrolysis of o-aminomethylphenols and their ammonium salts. Russ Chem Bull 31, 72–75 (1982). https://doi.org/10.1007/BF00954412

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  • DOI: https://doi.org/10.1007/BF00954412

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