Conclusions
Contrary to the previously described results, the reaction of theβ-oxoalkylidenetriphenylphosphoranes with the acid chlorides of the p-nitrobenzoic, cinnamic, and phenylacetic acids gives only the acyloxyvinylphosphonium salts. As a result, all of the currently known reactions of phosphorusβ-ketoylides with acid chlorides lead to the O-acylation products.
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Literature cited
N. A. Nesmeyanov, S. T. Berman, P. V. Petrovskii, A. I. Lutsenko, and O. A. Reutov, Zh. Org. Khim.,13, 2467 (1977).
N. A. Nesmeyanov, S. T. Berman, P. V. Petrovskii, and O. A. Reutov, Izv. Akad. Nauk SSSR, Ser. Khim.,1980, 2805.
S. T. Gough and S. Trippett, J. Chem. Soc.,1962, 2333.
P. A. Chopard, J. G. Searle, and P. H. Devitt, J. Org. Chem.,30, 1015 (1965).
A. V. Dombrovskii, V. N. Listvan, A. A. Grigorenko, and M. I. Shevchuk, Zh. Obshch. Khim.,36, 1421 (1966).
M. I. Shevchuk, E. M. Volynskaya, and A. V. Dombrovskii, Zh. Obshch. Khim.,40, 48 (1970).
F. Ramirez and S. Dershowits, J. Org. Chem.,22, 41 (1957).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 192–194, January, 1982.
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Nesmeyanov, N.A., Berman, S.T., Rebrova, O.A. et al. Acylation of phosphorusβ-ketoylides by acid chlorides. Russ Chem Bull 31, 181–183 (1982). https://doi.org/10.1007/BF00954436
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DOI: https://doi.org/10.1007/BF00954436