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Transformations of n-pentane, n-hexane, and benzene on high-silica zeolites containing group VIII metals

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It was found that reactions of hydrocracking and hydrogenolysis of n-pentane and n-hexane take place intensively on high-silica zeolites containing rhodium, iridium, ruthenium, and nickel, in contrast to pallasium-containing zeolites, which are active and selective catalysts of isomerization of n-pentane.

  2. 2.

    Rhodium and iridium zeolite catalysts also exhibit very high activity in the hydrogenation of benzene. At 100–120°C and atmospheric pressure, benzene is selectively hydrogenated into cyclohexane, which is not obtained on the other metal-containing zeolite catalysts investigated.

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Literature cited

  1. I. V. Kalechits, Vestn. Akad. Nauk SSSR, No. 5, 55 (1981).

    Google Scholar 

  2. Kh. M. Minachev and Ya. I. Isakov, Khim. Tverd. Topliva, No. 6, 7 (1982).

    Google Scholar 

  3. Kh. M. Minachev, D. A. Kondrat'ev, A. A. Dergachev, I. V. Mishin, I. N. Oleshko, B. K. Nefedov, and T. V. Alekseeva, Izv. Akad. Nauk SSSR, Ser. Khim., 1706 (1982).

  4. Kh. M. Minachev, V. I. Garanin, T. A. Isakova, I. L. Mironova, A. S. Fomin, and B. A. Lipkind, in: Use of Zeolites in Catalysis, III All-Union Conference [in Russian], Moscow (1981), p. 100.

  5. Kh. M. Minachev, V. I. Garanin, T. A. Isakova, I. L. Mironova, A. S. Fomin, and B. A. Lipkind, Izv. Akad. Nauk SSSR, Ser. Khim., 1227 (1982).

  6. Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, T. A. Isakova, and É. É. Senderov, Izv. Akad. Nauk SSSR, Ser. Khim., 1737 (1969).

  7. A. A. Klyachko, G. I. Kapustin, G. O. Glonti, T. R. Brueva, and A. M. Rubinshtein, Proceedings of the 6th Soviet-French Seminar on Catalysis [in Russian], Moscow (1983), p. 83.

  8. L. M. Kustov, V. Yu. Borokov, and V. B. Kazanskii, Proceedings of the 6th Soviet-French Seminar on Catalysis [in Russian], Moscow (1983), p. 63.

  9. Kh. M. Minachev, and Ya. I. Isakov, in: Metal-Containing Zeolites in Catalysis [in Russian], Nauka, Moscow (1976), p. 56.

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. I. Garanin, I. L. Mironova, A. S. Fomin & Kh. M. Minachev

Authors
  1. V. I. Garanin
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  2. I. L. Mironova
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  3. A. S. Fomin
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  4. Kh. M. Minachev
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1732–1736, August, 1986.

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Garanin, V.I., Mironova, I.L., Fomin, A.S. et al. Transformations of n-pentane, n-hexane, and benzene on high-silica zeolites containing group VIII metals. Russ Chem Bull 35, 1572–1575 (1986). https://doi.org/10.1007/BF00954588

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  • DOI: https://doi.org/10.1007/BF00954588

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