Conclusions
-
1.
The significant effect of the nature and method of addition of the modifying additive (boron, aluminum, rare-earth elements, platinum) on the properties of catalysts for conversion of methanol into hydrocarbons was demonstrated; catalysts prepared by the exchange method exhibited higher activity and stability.
-
2.
The nature and amount of the matrix have a large effect on the catalytic properties of HS zeolite catalysts in transformations of methanol. The HTsVM/Al2O3 (HTsVM ≥ 50%) composite is best in the conditions studied.
-
3.
An active and stable catalyst for conversion of methanol into hydrocarbons which worked for more than 500 h was developed based on the data obtained.
Similar content being viewed by others
Literature cited
C. D. Chang, Catal. Rev.,25, 1 (1983).
W. W. Kaeding and S. A. Butter, J. Catal.,61, 155 (1980).
J. C. Vedrine, A. Auroux, P. Dejaifve, V. Ducarme, H. Hoser, and S. Zhou, J. Catal.,73, No. 1, 147 (1982).
T. Inui, O. Yamase, K. Fukuda, A. Itoh, J. Tarumoto, J. Morinaga, T. Hagiwara, and T. Takegami, 8th International Congress on Catalysis, Vol. 3, West Berlin (1984), p. 569.
Cr. Pop, G. Musca, S. Serban, E. Pop, and P. Tomi, 8th International Congress on Catalysis, Vol. 3, West Berlin (1984), p. 559.
V. Yu. Volkov, M. A. Kaliko, B. A. Lipkind, and V. V. Zadymov, Khim. Takh. Topliv Masel, No. 6, 8 (1982).
O. V. Bragin, A. V. Preobrazhenskii, and A. L. Liberman, Izv. Akad. Nauk SSSR, Ser. Khim., 2751 (1974).
O. V. Bragin, T. B. Vasina, A. V. Preobrazhenskii, V. N. Lutovinova, and A. L. Liberman, Izv. Akad. Nauk SSSR, Ser. Khim., 2282 (1977).
O. V. Bragin, T. V. Vasina, V. N. Lutovinova, B. K. Nefedov, T. V. Alekseeva, and Kh. M. Minachev, Izv. Akad. Nauk SSSR, Ser. Khim., 626 (1982).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1487–1492, July, 1986.
Rights and permissions
About this article
Cite this article
Vasina, T.V., Khelkovskaya-Sergeeva, E.G., Rostanin, N.N. et al. Conversion of methanol into hydrocarbons in the presence of modified high-silicon zeolite catalysts. Russ Chem Bull 35, 1347–1351 (1986). https://doi.org/10.1007/BF00954797
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00954797