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Alkoxycarbonylation and amidation of aryl iodides catalyzed by palladium complexes

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Tin and sodium alkoxides, as well as tin amides, can be used as coreagents in the palladium complex-catalyzed carbonylation of aryl iodides. The use of such powerful nucleophiles as metal alkoxides and amides permits the carbonylation reactions to be carried out under milder conditions and at faster rates than those described in the literature.

  2. 2.

    A mechanism for the alkoxycarbonylation and amidation of aryl halides has been proposed based on results obtained using stoichiometric reactions of palladium complexes.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    N. A. Bumagin, Yu. V. Gulevich & I. P. Beletskaya

  2. L. Ya. Karpov Institute of Physical Chemistry, Moscow

    N. A. Bumagin, Yu. V. Gulevich & I. P. Beletskaya

Authors
  1. N. A. Bumagin
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  2. Yu. V. Gulevich
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  3. I. P. Beletskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1649–1656, July, 1986.

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Bumagin, N.A., Gulevich, Y.V. & Beletskaya, I.P. Alkoxycarbonylation and amidation of aryl iodides catalyzed by palladium complexes. Russ Chem Bull 35, 1498–1504 (1986). https://doi.org/10.1007/BF00954834

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  • DOI: https://doi.org/10.1007/BF00954834

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