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Formation of cyclopropane in the reaction of the components of complex metathesis catalyst

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Cyclopropane (the product from the reaction of the carbene with the olefin) is formed in the reaction of the components of the metathesis catalyst having the composition MoCl3(C17H35COO)2-Al(C2H5)2Cl.

  2. 2.

    Cyclopropane is not formed in the presence of cyclopentene and vinyltrimethylsilane, which trap the carbene active centers.

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Authors and Affiliations

  1. L. Ya. Karpov Physicochemical Institute, Moscow

    N. I. Pakuro, A. R. Gantmakher & B. A. Dolgoplosk

Authors
  1. N. I. Pakuro
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  2. A. R. Gantmakher
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  3. B. A. Dolgoplosk
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1052–1055, May, 1981.

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Pakuro, N.I., Gantmakher, A.R. & Dolgoplosk, B.A. Formation of cyclopropane in the reaction of the components of complex metathesis catalyst. Russ Chem Bull 30, 813–815 (1981). https://doi.org/10.1007/BF00955290

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  • DOI: https://doi.org/10.1007/BF00955290

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