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Reactions of organomagnesium compounds with allyl sulfones, catalyzed by transition metal salts

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reactions of Grignard reagents of various types with allyl sulfones in the presence of salts of transition metals have been studied, leading to the formation of unsaturated hydrocarbons. It has been found that Cu and Fe complexes, modified by PPh3, are the most active catalysts for this reaction.

  2. 2.

    It has been shown for the first time to be possible to effect the cross-coupling of allyl sulfones with symmetrical and nonsymmetrical magnesium dialkyls in the presence of copper complexes.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa

    A. G. Ibragimov, D. L. Minsker, R. A. Saraev & U. M. Dzhemilev

Authors
  1. A. G. Ibragimov
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  2. D. L. Minsker
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  3. R. A. Saraev
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  4. U. M. Dzhemilev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2333–2336, October, 1983.

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Ibragimov, A.G., Minsker, D.L., Saraev, R.A. et al. Reactions of organomagnesium compounds with allyl sulfones, catalyzed by transition metal salts. Russ Chem Bull 32, 2104–2107 (1983). https://doi.org/10.1007/BF00955781

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  • DOI: https://doi.org/10.1007/BF00955781

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