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Reaction of organogermanium bromides with samarium and ytterbium

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of R3GeBr (R=Et and Ph) with Sm and Ph gives Grignard-type reagents, R3GeLnBr.

  2. 2.

    The reaction of R3GeLnBr complexes with PhOH, EtBr, PhBr, Et3GeBr and (C6F5)3GeBr give Et3GeH, Et4Ge, Ph4Ge, Et4Ge2 and Et3GeGe(C6F5)3, respectively.

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Literature cited

  1. L. N. Bochkarev, M. N. Kholodilova, S. F. Zhil'tsov, et al., Zh. Obshch. Khim.,56, 723 (1986).

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  2. H. Schumann, Angew. Chem.,96, 475 (1985).

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  3. M. N. Bochkarev, N. Z. Vyazankin, L. N. Bochkarev, and G. A. Razuvayev, J. Organometall. Chem.,110, 149 (1976).

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of the USSE, Gorkii

    L. N. Bochkarev, I. L. Fedyushkin, M. N. Kholodilova, S. F. Zhit'tsov, M. N. Bochkarev & G. A. Razuvaev

Authors
  1. L. N. Bochkarev
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  2. I. L. Fedyushkin
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  3. M. N. Kholodilova
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  4. S. F. Zhit'tsov
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  5. M. N. Bochkarev
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  6. G. A. Razuvaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 658–659, March, 1987.

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Bochkarev, L.N., Fedyushkin, I.L., Kholodilova, M.N. et al. Reaction of organogermanium bromides with samarium and ytterbium. Russ Chem Bull 36, 600–602 (1987). https://doi.org/10.1007/BF00955849

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  • DOI: https://doi.org/10.1007/BF00955849

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