Skip to main content
SpringerLink
Log in

Mass spectrometry of transition metal π-complexes Communication 36. (η4-Norbornadiene)(acetylacetonato)rhodium(I) derivatives

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A mass spectral study of (norbornadiene)(acetylacetonato)rhodium derivatives showed that [Rh-norbornadiene]+ ions are more stable than [acacRh]+ ions. The decomposition of the molecular ions of these compounds with cleavage of the metal-ligand bonds is accompanied by a series of hydrogen rearrangements due to the migration of a hydrogen atom from the ligands to the metal atom or another ligand.

  2. 2.

    The greatest stability among the fragment ions, in which the bond of the metal atom with both ligands is retained, is found for ions characterized by a 16-electron shell of the rhodium atom and its oxidation state of +3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. V. Malkov, E. V. Leonova, D. V. Zagorevskii, and Yu. S. Nekrasov, Izv. Akad. Nauk SSSR, Ser. Khim., 1024 (1986).

  2. D. V. Zagorevskii, Yu. S. Nekrasov, I. T. Chizhevskii, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2701 (1982).

  3. M. Ryska, K. Bouchal, and F. Hrabak, J. Organomet. Chem.,51, 353 (1973).

    Google Scholar 

  4. D. V. Zagorevskii, V. A. Nikanorov, B. I. Ginzburg, V. I. Rozenberg, Yu. S. Nekrasov, and O. A. Reutov, Izv. Akad. Nauk SSSR, Ser. Khim., 1081 (1986).

  5. D. V. Zagorevskii, V. A. Nikanorov, B. I. Ginzburg, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1088 (1986).

  6. J. Müller and L. D'Or, J. Organomet. Chem.,10, 313 (1967).

    Google Scholar 

  7. Yu. S. Nekrasov, V. F. Sizoi, D. V. Zagorevskii, and N. I. Vasyukova, Org. Mass Spectrora.,10, 22 (1979).

    Google Scholar 

  8. Yu. S. Nekrasov, Doctoral Dissertation, Moscow (1982).

  9. A. A. Koridze, I. T. Chizhevskii(Chizhevsky), P. V. Petrovskii, et al., J. Organomet. Chem.,206, 373 (1981).

    Google Scholar 

  10. I. T. Chizhevskii, A. A. Koridze, P. V. Petrovskii, N. E. Kolobova, Izv. Akad. Nauk SSSR, Ser. Khim., 1124 (1981).

  11. I. T. Chizhevskii, N. V. Rastova, N. E. Kolobova, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1382 (1985).

  12. Yu. N. Sukharev and Yu. S. Nekrasov, Org. Mass Spectrom.,11, 1232 (1976).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    Yu. S. Nekrasov, D. V. Zagorevskii, N. V. Gérbéléu, S. P. Palii, I. T. Chizhevskii, N. V. Rastova & N. E. Kolobova

  2. Institute of Chemistry, Academy of Sciences of the Moldavian SSR, Kishinev

    Yu. S. Nekrasov, D. V. Zagorevskii, N. V. Gérbéléu, S. P. Palii, I. T. Chizhevskii, N. V. Rastova & N. E. Kolobova

Authors
  1. Yu. S. Nekrasov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. V. Zagorevskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. V. Gérbéléu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. P. Palii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. T. Chizhevskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. N. V. Rastova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. N. E. Kolobova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Communication 35, see ref. [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1029–1033, May, 1987.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nekrasov, Y.S., Zagorevskii, D.V., Gérbéléu, N.V. et al. Mass spectrometry of transition metal π-complexes Communication 36. (η4-Norbornadiene)(acetylacetonato)rhodium(I) derivatives. Russ Chem Bull 36, 947–951 (1987). https://doi.org/10.1007/BF00956343

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00956343

Keywords

Search

Navigation