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Enhanced stability of the oxygen complex of Co(II) protoporphyrin IX upon its association with cyclodextrins

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Co-Protoporphyrin forms a pentacoordinated complex with imidazole which binds O2 in DMF solution.

  2. 2.

    Upon association with cyclodextrin, the resistance of the O2CoPP-imidazole complex toward autoxidation is markedly enhanced.

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Literature cited

  1. A. A. Shteinman, Izv. Akad. Nauk SSSR, Ser. Khim., 2415 (1983).

  2. A. B. Sorokin and A. A. Shteinman, Izv. Akad. Nauk SSSR, Ser. Khim., 1452 (1985).

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Authors and Affiliations

  1. Institute of Chemical Physics, Chernogolovka Branch, Academy of Sciences of the USSR, USSR

    A. V. Kulikov, E. V. Trushina & A. A. Shteinman

Authors
  1. A. V. Kulikov
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  2. E. V. Trushina
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  3. A. A. Shteinman
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2839–2841, December, 1987.

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Kulikov, A.V., Trushina, E.V. & Shteinman, A.A. Enhanced stability of the oxygen complex of Co(II) protoporphyrin IX upon its association with cyclodextrins. Russ Chem Bull 36, 2636–2638 (1987). https://doi.org/10.1007/BF00957253

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  • DOI: https://doi.org/10.1007/BF00957253

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