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Oxidation of di-tert-alkylhydroxylamines to nitroxide radicals by nitrous acid

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have developed a convenient preparative method for obtaining nitroxide radicals by oxidation of di-tert-alkylhydroxylamines and their salts by nitrous acid.

  2. 2.

    We propose protection of the nitride functional group by conversion of the nitroxide radical to the salt of the hydroxylamine, and removal of the protection by oxidation with nitrous acid.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    L. A. Krinitskaya & L. B. Volodarskii

  2. Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    L. A. Krinitskaya & L. B. Volodarskii

Authors
  1. L. A. Krinitskaya
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  2. L. B. Volodarskii
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Translated from Izvestiya Akademiya Nauk SSSR, Seriya Khimiya, No. 2, pp. 391–394, February, 1983.

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Krinitskaya, L.A., Volodarskii, L.B. Oxidation of di-tert-alkylhydroxylamines to nitroxide radicals by nitrous acid. Russ Chem Bull 32, 352–355 (1983). https://doi.org/10.1007/BF00957948

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  • DOI: https://doi.org/10.1007/BF00957948

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