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3-Hydroperfluoro-2-butanone and its reactions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    3-Hydroperfluoro-2-butanone was synthesized in ∼90% yield by the hydrolysis of 2-methoxy-3-hydroperfluorobutane with 60% oleum.

  2. 2.

    The haloform splitting of 3-hydroperfluoro-2-butanone is hindered when compared with perfluoroketones.

  3. 3.

    The action of NH3, LiAlH4, and PCl5 respectively gave 2-hydroxy-2-amino-3-hydroperfluorobutane, 2,3-dihydroperfluoro-2-butanol, and a mixture of 2,2,3-trichloroheptafluorobutane and 2-chloroheptafluoro-2-butene.

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Literature cited

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Authors and Affiliations

  1. Chemistry Institute, Ural Science Center, Academy of Sciences of the USSR, Sverdlovsk

    L. V. Saloutina, A. Ya. Zapevalov, M. I. Kodess, I. P. Kolenko & L. S. German

  2. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. V. Saloutina, A. Ya. Zapevalov, M. I. Kodess, I. P. Kolenko & L. S. German

Authors
  1. L. V. Saloutina
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  2. A. Ya. Zapevalov
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  3. M. I. Kodess
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  4. I. P. Kolenko
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  5. L. S. German
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2615–2617, November, 1982.

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Saloutina, L.V., Zapevalov, A.Y., Kodess, M.I. et al. 3-Hydroperfluoro-2-butanone and its reactions. Russ Chem Bull 31, 2310–2312 (1982). https://doi.org/10.1007/BF00958424

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  • DOI: https://doi.org/10.1007/BF00958424

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