Abstract
A method has been developed for effecting rearrangements of allylacetoacetates to γ,δ-unsaturated ketones (Carroll rearrangement) and allylaryl ethers to the corresponding allylphenols (Claisen rearrangement) under conditions of adsorption on aluminum oxide and silica gel. The method provides a sharp reduction of the temperature of these reactions and improvement of their efficiency.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 835–842, April, 1991.
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Pogrebnoi, S.I., Kal'yan, Y.B., Krimer, M.Z. et al. [3,3]-Sigmatropic rearrangements of the acetoacetates of allyl alcohols (Carroll reaction) and allylphenyl ethers (Claisen reaction) on the surface of adsorbents. Russ Chem Bull 40, 733–739 (1991). https://doi.org/10.1007/BF00958563
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DOI: https://doi.org/10.1007/BF00958563