Abstract
A number of stable bis(nitrile oxides) based on dimesitylmethane and didurylmethane and their analogs in which two aromatic rings are joined by various bridging groups were synthesized. The thermal isomerization of the bis(nitrile oxides) to diisocyanates and the relative reactivities of the bis(nitrile oxides) in 1,3-dipolar cycloaddition to styrene were studied.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1398–1403, June, 1991.
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Tsyganov, D.V., Yakubov, A.P., Belen'kii, L.I. et al. Synthesis and properties of stable aromatic bis(nitrile oxides). Russ Chem Bull 40, 1238–1243 (1991). https://doi.org/10.1007/BF00961305
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DOI: https://doi.org/10.1007/BF00961305