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Heterogeneous phase transfer catalysts 1. Synthesis and catalytic properties of polymeric crown-ethers on inorganic supports

  • Inorganic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

A number of new heterogeneous phase transfer catalysts based on polymeric dibenzo-crown-ethers supported on the carbonaceous material “Sibunite”, ultrafine diamonds, or silica gel are synthesized. The activity of several of the catalysts for the reaction of 1-bromooctane with KI is higher than that of previously known analogs. The catalytic effect depends on the support, linker, and solvent.

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Literature cited

  1. A. Kh. Zitsmanis, M. K. Klyavin'sh, A. S. Roska, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 387 (1987).

  2. E. Demlov and Z. Demlov, Phase-transfer Catalysis [Russian translation], Mir, Moscow (1987).

    Google Scholar 

  3. M. Hiraoka, Crown Compounds [Russian translation], Mir, Moscow (1986).

    Google Scholar 

  4. Y. I. Ermakov, V. F. Surovikin, G. V. Plaksin, et al., React Kinet. Catal. Lett.,33, 435 (1987).

    Google Scholar 

  5. A. I. Lyamkin, E. A. Petrov, A. P. Ershov, et al., Dokl. Akad. Nauk SSSR,302, No. 3, 611 (1988).

    Google Scholar 

  6. F. Svec, Pure Appl. Chem.,60, 377 (1988).

    Google Scholar 

  7. A. B. Zhidkov, S. K. Gordeev, E. P. Smirnov, and S. V. Novikov, Zh. Prikl. Khim., (Leningrad),57, No. 11, 2429 (1984); All-Union Institute of Scientific and Technical Information, deposited paper No. 6912-V85 (1985).

    Google Scholar 

  8. A. Yu. Tsivadze, N. B. Generalova, E. Kh. Pyatova, et al., Zh. Neorg. Khim.,33, 1649 (1988).

    Google Scholar 

  9. Y. Gui, B. Liu, J. Liu, et al., Youji Huaxue, No. 5, 373 (1986).

    Google Scholar 

  10. P. Hodge, E. Khoshdel, and J. Waterhouse, J. Chem. Soc. Perkin Trans, 1, 2451 (1984).

    Google Scholar 

  11. S. L. Regen, Angew. Chem. Int. Ed. Eng.,18, 421 (1979).

    Google Scholar 

  12. A. A. Klesov and I. V. Berzin, Enzyme Catalysis [in Russian], Izd. Mosk. Univ., Moscow (1980), pp. 12–19.

    Google Scholar 

  13. K. Fukunishi, B. Czech, and S. L. Regen, J. Org. Chem.,46, 1218 (1981).

    Google Scholar 

  14. A. K. Tashmukhamedova, I. A. Stempnevskaya, I. Yu. Morozova, and E. G. Siromenko, Khim. Geterotsikl. Soedin., No. 4, 470 (1989).

    Google Scholar 

  15. V. F. Loktev, I. Yu. Morozova, and A. K. Tashmukhamedova, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 119 (1989).

  16. Methoden der Organischen Chemie, Vol. 14/2, Georg. Tieme Verlag, Stuttgart (1963), p. 1252.

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Authors and Affiliations

  1. Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    V. F. Loktev, I. Yu. Morozova, A. K. Tashmukhamedova & V. A. Likholobov

  2. Tashkent State University, USSR

    V. F. Loktev, I. Yu. Morozova, A. K. Tashmukhamedova & V. A. Likholobov

Authors
  1. V. F. Loktev
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  2. I. Yu. Morozova
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  3. A. K. Tashmukhamedova
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  4. V. A. Likholobov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1257–1262. June. 1990.

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Loktev, V.F., Morozova, I.Y., Tashmukhamedova, A.K. et al. Heterogeneous phase transfer catalysts 1. Synthesis and catalytic properties of polymeric crown-ethers on inorganic supports. Russ Chem Bull 39, 1128–1132 (1990). https://doi.org/10.1007/BF00962368

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  • DOI: https://doi.org/10.1007/BF00962368

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