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Mechanism of the reaction of ozone with phenols

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

An investigation has been carried out into the composition of the products of the O3 reaction with PhOH in different solvents and into the kinetics of their build-up. A scheme is proposed for the reaction in which the first stage, which limits the rate of the entire process, is formation of a complex of O3 with the PhOH hydroxy group. Formation of muconic acid does not require the participation of H2O.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    M. L. Konstantinova, S. D. Razumovskii & G. E. Zaikov

Authors
  1. M. L. Konstantinova
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  2. S. D. Razumovskii
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  3. G. E. Zaikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 324–328, February, 1991.

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Konstantinova, M.L., Razumovskii, S.D. & Zaikov, G.E. Mechanism of the reaction of ozone with phenols. Russ Chem Bull 40, 271–275 (1991). https://doi.org/10.1007/BF00965413

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  • DOI: https://doi.org/10.1007/BF00965413

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