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Synthesis, spectroscopy and thermal properties of the nickel(II), palladium(II) and copper(II) complexes of oxalyldihydrazide

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The new complexes K2[ML2]·2H2O (M=Ni, Cu), K2[PdL2]·H2O, K2[CuL2(H2O)2]·H2O, [Ni(LH2)Cl2]x ·xH2O and [Ni(LH2)Br2]x·1,5xH2O, where LH2= oxalyldihydrazide, have been prepared. Emphasis has been put on determining the conditions for the synthesis of both deprotonated and non-deprotonated NiII complexes. They were characterized by analyses, conductivity measurements, thermogravimetry, magnetic susceptibility and spectroscopic methods like i.r. and far-i.r., diffuse reflectance u.v. vis, and e.s.r. Monomeric square planar and distorted octahedral structures were found for the deprotonated complexes in the solid state while the non-deprotonated NiII complexes appeared to be pseudo-tetrahedral polymers. The doubly deprotonated L2-ion exhibits a bidentate N(amide), N(amide)-coordination, while the neutral LH2 molecule behaves as a N(amino), N(amino)-bidentate ligand forming polymeric structures. Vibrational analysis of the complexes was carried out, using hydrogen and metal isotopic substitution.

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Authors and Affiliations

  1. Laboratory of Inorganic Chemistry, Department of Chemistry, University of loannina, loannina, Greece

    Spyros P. Perlepes

  2. Laboratorium Anorganische Scheikunde, Rijksuniversitair Centrum Antwerpen, Groenenborgerlaan 171, 2020, Antwerpen, Belgium

    Frank J. Quaeyhaegens & Herman O. Desseyn

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  1. Spyros P. Perlepes
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  2. Frank J. Quaeyhaegens
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  3. Herman O. Desseyn
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Perlepes, S.P., Quaeyhaegens, F.J. & Desseyn, H.O. Synthesis, spectroscopy and thermal properties of the nickel(II), palladium(II) and copper(II) complexes of oxalyldihydrazide. Transition Met Chem 15, 132–140 (1990). https://doi.org/10.1007/BF01023902

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