Abstract
Liquid metal embrittlement is the reduction in the elongation to failure that can be produced when normally ductile solid metals are stressed while in contact with a liquid metal. This review describes its principal characteristics and the several models which have been advanced in attempts to explain the occurrence and different features of the process. Comparison between theory and experiment indicates that many, but not all, of its aspects are consistent with a mechanism which operates by reducing the fracture surface energy of the solid metal. Literature reports show that liquid metal embrittlement can occur with a very wide range of material combinations, and while most of the data refer to laboratory studies, it is clear that the phenomenon is also of technological significance as a potential cause of plant damage.
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References
A. R. C. Westwood, C. M. Preece andM. H. Kamdar, “Fracture” Vol. 3, edited by H. Leibowitz (Academic Press, London, 1971) p. 589.
A. K. Huntington,J. Inst. Met. 11 (1914) 108.
V. W. Eldred, AERE X/R 1806 (1955).
W. Rostoker, J. M. McCaughey andH. Markus, “Embrittlement of liquid metals” (Rheinhold, New York, 1960).
N. S. Stoloff, “Surfaces and Interfaces”, Vol. II, edited by J. J. Burkeet al. (Syracuse Univ. Press, 1968) p. 157.
M. H. Kamdar,Progr. Mater. Sci. 15 (1973) 289.
The Observer, Oct. 10th (1976).
“The Flixborough Disaster”, Report of the Court of Inquiry (HMSO, London, 1975).
L. S. Bryukhanova, J. A. Andreeva andV. I. Likhtman,Sov. Phys. Solid State 3 (1962) 2025.
C. M. Preece andA. R. C. Westwood, Proceedings of the 2nd International Conference on Fracture, edited by P. L. Pratt, (Chapman and Hall, London, 1969) p. 439.
N. M. Parikh, Conference on Environment Sensitive Mechanical Behaviour, edited by A. R. C. Westwood and N. S. Stoloff, (Gordon and Breach, New York, 1966) p. 563.
M. Tanaka andH. Fukanaga, Proceedings of the 12th Japanese Congress on Materials Research (Kyoto, 1969) p. 248.
N. S. Stoloff andT. L. Johnston,Acta. Met. 11 (1963) 251.
G. Herbsleb andW. Schwenk,Werkstoffe und Korrosion 28 (1977) 145.
P. Hancock andM. B. Ives,Can. Met. Qtly. 10 (1971) 203.
C. Roques-Carmes, M. Aucouturier andP. Lacombe,Can. Met. Qtly. 13 (1974) 115.
R. J. H. Wanhill,Corrosion-N.A.C.E. 30 (1974) 371.
W. T. Grubb,Nature 265 (1977) 36.
M. J. Blackburn, J. A. Feeney andT. R. Beck, “Advances in Corrosion Science and Technology”, Vol. 3, edited by M. G. Fontana and R. W. Staehle (Plenum Press, New York, 1973) p. 67.
A. H. Maitland andG. A. Chadwick,Phil. Mag. 19 (1969) 1305.
V. I. Likhtman, L. A. Kochanova andL. S. Bryukhanova,Sov. Phys. Dokl. 3 (1958) 599.
A. R. C. Westwood, C. M. Preece andM. H. Kamdar,Trans. ASM 60 (1967) 723.
M. H. Kamdar andA. R. C. Westwood,Phil. Mag. 15 (1967) 641.
W. Barclay andF. N. Rhines, unpublished work quoted in [4]“, p. 44.
C. F. Old, 4th International Conference on Fracture (University of Waterloo Press, 1977) p. 331.
H. Nichols andW. Rostoker,Acta Met. 8 (1960) 848.
C. F. Old andP. Trevena, AERE-R9226 (1978).
J. C. Lynn, W. R. Warke andP. Gordon,Mater. Sci. Eng. 18 (1975) 51.
F. A. Shunk, Ph. D. Thesis, I. I. T., (1969),Diss. Abs. B37 (1976).
H. Ichinose andG. Oouchi,Trans. Jap. Inst. Met. 9 (supplement) (1968) 980.
W. M. Robertson,Met. Trans. 1 (1970) 2607.
J. V. Rinnovatore, J. V. Corrie andH. Markus,Trans. ASM 59 (1966) 665.
W. R. Warke, 3rd Progress Report, Project Themis, AD 708377.
D. N. Fager andW. F. Spurr,Corrosion-N.A.C.E. 27 (1971) 72.
Idem, ibid. 26 (1970) 409.
D. A. Meyn,ibid. 29 (1973) 192.
Aluminium Development Association,Metallurgia 42 (1950) 131.
N. S. Stoloff, R. G. Davies andT. L. Johnston, Conference on Environment Sensitive Mechanical Behaviour, edited by A. R. C. Westwood and N. S. Stoloff, (Gordon and Breach, New York, 1966) p. 613.
R. Rosenberg andP. Cadoff, “Fracture of Solids”, edited D. C. Drucker and J. J. Gilman (Interscience, New York, 1963) p. 607.
H. Ichinose andG. Oouchi,Trans. Jap. Inst. Met. 10 (1969) 178.
H. Nichols andW. Rostoker,Trans. ASM 56 (1963) 494.
M. Watkins, L. Johnson andN. N. Breyer, 4th Interamerican Conference on Materials Technology (Caracas, 1975) p. 31.
L. P. Costas,Corrosion-N.A.C.E. 31 (1975) 91.
S. Dinda, andW. R. Warke,Mater. Sci. Eng. 24 (1976) 199.
C. M. Preece,Res. Dev. 23 (1972) 30.
H. Nichols andW. Rostoker,Trans. AIME 224 (1962) 1258.
M. D. Chadwick, R. B. Gibbon andD. Howel, IRD-64-55 and IRD-65-57.
W. R. Goggin andJ. W. Moberly,Trans. ASM Qtly. 59 (1966) 315.
M. Aucouturier, P. Lacombe andC. Roquescarmes,Compt. Rendus 270C (1970) 469.
Idem, Mem. Sci. Rev. Met. 67 (1970) 367.
C. Brichet, L. Peeters, C. Roques-Carmes andG. Wyon,Compt. Rendus 271C (1970) 617.
L. Peeters, C. Roques-Carmes, M. Aucouturier andG. Wyon,Mem. Sci. Rev. Met. 69 (1972) 81.
D. J. Goddard andJ. A. Williams,J. Inst. Met. 99 (1971) 323.
K. J. Goddard andC. A. P. Horton,Metallography 6 (1973) 131.
C. Roques-Carmes, M. Aucouturier andP. Lacombe,Metal Sci. 7 (1973) 128.
S. K. Marya andG. Wyon,Scripta Met. 9 (1975) 1009.
Idem, Metallography 9 (1976) 123.
C. F. Old, AERE-R8343 (1976).
F. N. Rhines, J. A. Alexander andW. F. Barclay,Trans. ASM 55 (1962) 22.
W. Rostoker, Armour Research Foundation Report B183 (1963).
H. Ichinose,Trans. Jap. Inst. Met. 9 (1968) 35.
M. J. Malm andC. M. Preece,Mater. Sci. Eng. 11 (1973) 223.
G. Wesley-Austin,J. Inst. Met. 58 (1936) 173.
W. R. Smith andP. E. J. Forsyth,Metallurgia 34 (1946) 186, 245.
Y. M. Potak andI. M. Shchlegakov,Zhur Tekh Fiz 25 (1955) 897.
N. V. Pertsov andP. A. Rebinder,Dokl. Akad. Nauk USSR 123 (1958) 1068.
P. D. Novokreshehenov andN. V. Savchenko,Dokl Akad Nauk, Tekh Fiz 148 (1963) 328.
R. W. Vook, Conference on Environment Sensitive Mechanical Behaviour, edited by A. R. C. Westwood and N. S. Stoloff (Gordon and Breach, New York, 1966) p. 657.
R. Chadwick,J. Inst. Met. 97 (1969) 93.
K. Nagata andS. Seto, Sumitomo Light Metal Technical Reports,10 (1969) 21.
M. M. Shea andN. S. Stoloff,Mater. Sci. Eng. 12 (1973) 245.
R. Eborall andP. Gregory,J. Inst. Met. 84 (1955–6) 88.
W. H. Bassett,Proc. ASTM 18 (1918) 153.
C. H. Desch,J. Inst. Met. 22 (1919) 247.
H. Moore andS. Beckinsale,J. Inst. Met. 23 (1920) 225.
H. Moore, S. Beckinsale andC. E. Malinson,ibid. 25 (1921) 33.
D. Crampton,Trans. AIME 89 (1930) 23.
W. Lynes,Proc. ASTM 41 (1941) 859.
T. C. Wilson, G. Edmunds, E. A. Anderson andW. H. Pierce, Symposium on Stress Corrosion Cracking (ASTM-AIME, Philadelphia, 1944) 173.
W. D. Robertson,J. Metals (1951) 1190.
W. D. Martin and G. C.Smith, private communication.
T. L. Johnston, R. G. Davies andN. S. Stoloff,Phil. Mag. 12 (1965) 305.
G. Edmunds, Symposium on stress corrosion cracking of metals (ASTM-AIME, Philadelphia, 1944) p. 67.
I. B. Cadoff, E. Levine andH. T. Michels,Met. Trans. 3 (1972) 2139.
S. Seelinger andN. S. Stoloff, “In-situ composites”, Vol. II (Gordon and Breach, New York, 1973) p. 223.
T. M. Regan andN. S. Stoloff,Met. Trans. 8A (1977) 885.
J. H. S. Dickinson,J. Inst. Met. 24 (1920) 315.
H. J. Miller,ibid. 37 (1927) 183.
M. E. Whittaker,Metallurgia 39 (1948) 21.
V. I. Likhtman, E. D. Shchukin andP. A. Rebinder, “Physico-Chemical Mechanics of Metals” (Acad. Sci. USSR, Moscow, 1962).
H. F. Hartley,J. Inst. Met. 37 (1962) 193.
B. D. Summ,Phys. Metals Metallog. 14 (1963) 104.
N. I. Flegontova, B. D. Summ andYú V. Goryunov,ibid. 18 (1964) 85.
M. H. Kamdar andA. R. C. Westwood, US Government Research Reports40 (1965) AD 613701.
V. Y. Traskin,Fiz Khim Mekh Met 1 (1965) 645.
C. F. Old andP. Trevena, AERE-R8311 (1976).
F. A. Shunk andW. R. Warke,Scripta Met. 8 (1974) 519.
V. N. Rozhanski, N. V. Pertsov, E. D. Shchukin andP. A. Rebinder,Dokl Akad Nauk USSR 116 (1957) 769.
G. S. Knishnik,Nauk Tr. Vses Zaoch Mashinostroit Inst. 12 (1975) 79.
E. D. Shchukin andV. I. Likhtman,Sov. Phys. Dokl 4 (1959) 111.
Yú V. Goryunova,Dokl Akad Nauk USSR 153 (1963) 634.
L. A. Kochanova, “The role of surface phenomena in metallurgy”, (Moscow Univ., 1963) p. 129.
A. R. C. Westwood andM. H. Kamdar,Phil. Mag. 8 (1963) 787.
A. R. C. Westwood,ibid. 9 (1964) 199.
B. D. Summ, L. V. Ivanova andYú V. Goryunova,Fiz. Khim Mekhan Mat. 1 (1965) 648.
M. H. Kamdar andA. R. C. Westwood, “Environment Sensitive Mechanical Behaviour” (Gordon and Breach, New York, 1966) p. 581.
A. R. C. Westwood, “Strengthening mechanisms—metal and ceramics” (Syracuse University Press, 1966) p. 407.
M. H. Kamdar andA. R. C. Westwood, International Conference on Strengths of Metals and Alloys (Jap. Inst. Metals, Sendai, 1968) p. 525.
Idem, US Government Research Reports68 (1968) AD 66866.
Idem, Acta. Met. 16 (1968) 1335.
A. H. Maitland andG. A. Chadwick,Phil. Mag. 19 (1969) 645.
M. H. Kamdar,Met. Trans. 2 (1971) 2937.
G. I. Denshehikova, Yú V. Goryunova, L. S. Soldatchenkova andB. D. Summ,Fiz. Khim Mekhan Mat. 11 (1975) 5.
N. J. E. Gunn, C. A. Stubbington andJ. T. Barlett, R. A. E. Tech. Memo Mat 233 (1975).
W. T. Grubb andM. H. Morgan III, American Nuclear Society Topical Meeting on Reactor Fuel Performance (1977).
E. G. Coleman, D. Weinstein andW. Rostoker,Acta, Met. 9 (1961) 491.
M. Tanaka andH. Fukunaga,J. Soc. Mater. Sci. (Jap.) 18 (1969) 411.
J. E. Cordwell, Proceedings of International Congress organised by the British Nuclear Energy Society, Nottingham (British Nuclear Energy Society, London, 1973) p. 177.
H. Schottky, K. Schiektel andR. Stolle,Arch Eisenhutten. 4 (1931) 541.
E. M. Kennedy Jr, Wadc TR 58–108 (1958) Astia 151075.
A. Kelly, W. R. Tyson andA. H. Cottrell,Phil. Mag. 15 (1967) 567.
J. F. Hildebrand,Mater Protection and Performance 12 (1973) 35.
W. Radeker,Werkstoffe und Korrosion 24 (1973) 851.
J. C. Lynn, Ph. D. Thesis, I.I.T. (1974).
N. N. Breyer andK. L. Johnson,J. Testing and Evaluation 2 (1974) 471.
S. M. Baranov andS. I. Karatushkin,Soviet Mater. Sci. 3 (1967) 101.
W. Herrnkind, 3rd International Conference on Lead (Venice, 1968) 387.
W. Warke, K. L. Johnson ANDN. N. Breyer, “Corrosion by liquid metals” (Plenum Press, New York, 1970) p. 417.
W. Warke andN. N. Breyer,J. Iron Steel Inst. (1971) 779.
H. W. Hayden andS. Floreen,Phil. Mag. 20 (1969) 135.
L. J. G. vanEwijk,J. Inst. Met. 56 (1935) 241.
W. E. Goodrich,J. Iron Steel Inst. 132 (1935) 63.
M. S. Wang, M. Sc. Thesis, Leeds (1943).
R. Genders,J. Inst. Met. 37 (1927) 215.
G. F. Kosogov andV. I. Likhtman,Soviet Phys. Dokl. 5 (1960) 1054.
F. Page,Proc. Amer. Electroplaters Soc. (1943) 51.
W. Radecker,Stahl und Eisen 73 (1973) 654.
M. Andreani, P. Azou andP. Bastien,C. R. Acad. Sci. Paris 263C (1966) 1041.
M. Andreani, P. Azou andO. Bastien,Mem. Sci. Rev. Met. 66 (1969) 21.
J. E. Cantwell andR. E. Bryant, Hydrocarbon Processing, May (1973) p. 114.
A. H. Cottrell andP. R. Swann,Chem. Eng. (London) (1976) 266.
V. L. Kolmogorov, V. A. Chichigin, V. G. Burdukovsky andB. A. Antoshechkin,Russ. Met. 1 (1976) 61.
R. R. Hough andR. Rolls,Scripta Met. 4 (1970) 17.
Idem, J. Mater. Sci. 6 (1971) 1493.
Idem, Scripta Met. 8 (1974) 39.
British Engine Technical Reports6 (1965) 76.
Ibid. 7 (1966) 42.
Ibid. 11 (1972) 63.
J. G. Ball,Chem. Eng. (London) (1976) 275.
W. M. Robertson,Trans. AIME 236 (1966) 1478.
M. J. Kelley andN. S. Stoloff,Met. Trans. A 6A (1975) 159.
S. P. Lynch, Proceedings of the 4th International Conference on Fracture,11 Vol. 2 (University of Waterloo Press, 1977) p. 859.
V. M. Zalkin,Sov. Mater. Sci. 4 (1968) 18.
M. A. Krishtal,ibid. 5 (1969) 537.
E. D. Shchukin andV. S. Yushchenko,ibid. 2 (1966) 95.
C. M. Preece andA. R. C. Westwood,Trans. ASM 62 (1969) 418.
A. A. Griffith,Phil. Trans. Roy. Soc. 221A (1920) 163.
C. E. Inglis,Trans. Inst. Naval Architects 55 (1913) 219.
C. Zener, “Fracturing of Metals” (ASM, Metals Park, Ohio, 1943) p. 3.
N. J. Petch, “Fracture”, Proceedings of the Swampscott Conference, (1959) edited by B. L. Averbachet al. (John Wiley, New York, 1959) p. 54.
A. N. Stroh,Adv. Phys. 6 (1957) 418.
E. D. Hondros,Phil Mag. 29 (1974) 771.
M. I. Chaevskii,Sov. Mater. Sci. 1 (1965) 433.
M. I. Chaevskii andV. V. Popovich,ibid. 2 (1966) 102.
I. N. Toropovskaya,ibid. 6 (1970) 324.
A. S. Tetelman andS. Kunz, Technical Report Contract DAHC-04-69-C-0008, UCLA (1973).
B. C. Edwards, H. E. Bishop, J. C. Riviere andB. L. Eyre, Aere R8298 (1976).
E. Levine, H. Solomon andI. Cadoff,Acta. Met. 12 (1964) 119.
A. W. Thompson andI. M. Bernstein, 4th International Conference on Fracture, (University of Waterloo Press, 1977) p. 249.
H. Allsop, RAE TR 77014.
M. Barlow andP. J. Planting,Z. Metall 60 (1969) 817.
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Nicholas, M.G., Old, C.F. Liquid metal embrittlement. J Mater Sci 14, 1–18 (1979). https://doi.org/10.1007/BF01028323
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DOI: https://doi.org/10.1007/BF01028323