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Liquid metal embrittlement

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Abstract

Liquid metal embrittlement is the reduction in the elongation to failure that can be produced when normally ductile solid metals are stressed while in contact with a liquid metal. This review describes its principal characteristics and the several models which have been advanced in attempts to explain the occurrence and different features of the process. Comparison between theory and experiment indicates that many, but not all, of its aspects are consistent with a mechanism which operates by reducing the fracture surface energy of the solid metal. Literature reports show that liquid metal embrittlement can occur with a very wide range of material combinations, and while most of the data refer to laboratory studies, it is clear that the phenomenon is also of technological significance as a potential cause of plant damage.

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References

  1. A. R. C. Westwood, C. M. Preece andM. H. Kamdar, “Fracture” Vol. 3, edited by H. Leibowitz (Academic Press, London, 1971) p. 589.

    Google Scholar 

  2. A. K. Huntington,J. Inst. Met. 11 (1914) 108.

    Google Scholar 

  3. V. W. Eldred, AERE X/R 1806 (1955).

  4. W. Rostoker, J. M. McCaughey andH. Markus, “Embrittlement of liquid metals” (Rheinhold, New York, 1960).

    Google Scholar 

  5. N. S. Stoloff, “Surfaces and Interfaces”, Vol. II, edited by J. J. Burkeet al. (Syracuse Univ. Press, 1968) p. 157.

  6. M. H. Kamdar,Progr. Mater. Sci. 15 (1973) 289.

    Google Scholar 

  7. The Observer, Oct. 10th (1976).

  8. “The Flixborough Disaster”, Report of the Court of Inquiry (HMSO, London, 1975).

  9. L. S. Bryukhanova, J. A. Andreeva andV. I. Likhtman,Sov. Phys. Solid State 3 (1962) 2025.

    Google Scholar 

  10. C. M. Preece andA. R. C. Westwood, Proceedings of the 2nd International Conference on Fracture, edited by P. L. Pratt, (Chapman and Hall, London, 1969) p. 439.

    Google Scholar 

  11. N. M. Parikh, Conference on Environment Sensitive Mechanical Behaviour, edited by A. R. C. Westwood and N. S. Stoloff, (Gordon and Breach, New York, 1966) p. 563.

    Google Scholar 

  12. M. Tanaka andH. Fukanaga, Proceedings of the 12th Japanese Congress on Materials Research (Kyoto, 1969) p. 248.

  13. N. S. Stoloff andT. L. Johnston,Acta. Met. 11 (1963) 251.

    Google Scholar 

  14. G. Herbsleb andW. Schwenk,Werkstoffe und Korrosion 28 (1977) 145.

    Google Scholar 

  15. P. Hancock andM. B. Ives,Can. Met. Qtly. 10 (1971) 203.

    Google Scholar 

  16. C. Roques-Carmes, M. Aucouturier andP. Lacombe,Can. Met. Qtly. 13 (1974) 115.

    Google Scholar 

  17. R. J. H. Wanhill,Corrosion-N.A.C.E. 30 (1974) 371.

    Google Scholar 

  18. W. T. Grubb,Nature 265 (1977) 36.

    Google Scholar 

  19. M. J. Blackburn, J. A. Feeney andT. R. Beck, “Advances in Corrosion Science and Technology”, Vol. 3, edited by M. G. Fontana and R. W. Staehle (Plenum Press, New York, 1973) p. 67.

    Google Scholar 

  20. A. H. Maitland andG. A. Chadwick,Phil. Mag. 19 (1969) 1305.

    Google Scholar 

  21. V. I. Likhtman, L. A. Kochanova andL. S. Bryukhanova,Sov. Phys. Dokl. 3 (1958) 599.

    Google Scholar 

  22. A. R. C. Westwood, C. M. Preece andM. H. Kamdar,Trans. ASM 60 (1967) 723.

    Google Scholar 

  23. M. H. Kamdar andA. R. C. Westwood,Phil. Mag. 15 (1967) 641.

    Google Scholar 

  24. W. Barclay andF. N. Rhines, unpublished work quoted in [4]“, p. 44.

    Google Scholar 

  25. C. F. Old, 4th International Conference on Fracture (University of Waterloo Press, 1977) p. 331.

  26. H. Nichols andW. Rostoker,Acta Met. 8 (1960) 848.

    Google Scholar 

  27. C. F. Old andP. Trevena, AERE-R9226 (1978).

  28. J. C. Lynn, W. R. Warke andP. Gordon,Mater. Sci. Eng. 18 (1975) 51.

    Google Scholar 

  29. F. A. Shunk, Ph. D. Thesis, I. I. T., (1969),Diss. Abs. B37 (1976).

  30. H. Ichinose andG. Oouchi,Trans. Jap. Inst. Met. 9 (supplement) (1968) 980.

    Google Scholar 

  31. W. M. Robertson,Met. Trans. 1 (1970) 2607.

    Google Scholar 

  32. J. V. Rinnovatore, J. V. Corrie andH. Markus,Trans. ASM 59 (1966) 665.

    Google Scholar 

  33. W. R. Warke, 3rd Progress Report, Project Themis, AD 708377.

  34. D. N. Fager andW. F. Spurr,Corrosion-N.A.C.E. 27 (1971) 72.

    Google Scholar 

  35. Idem, ibid. 26 (1970) 409.

    Google Scholar 

  36. D. A. Meyn,ibid. 29 (1973) 192.

    Google Scholar 

  37. Aluminium Development Association,Metallurgia 42 (1950) 131.

    Google Scholar 

  38. N. S. Stoloff, R. G. Davies andT. L. Johnston, Conference on Environment Sensitive Mechanical Behaviour, edited by A. R. C. Westwood and N. S. Stoloff, (Gordon and Breach, New York, 1966) p. 613.

    Google Scholar 

  39. R. Rosenberg andP. Cadoff, “Fracture of Solids”, edited D. C. Drucker and J. J. Gilman (Interscience, New York, 1963) p. 607.

    Google Scholar 

  40. H. Ichinose andG. Oouchi,Trans. Jap. Inst. Met. 10 (1969) 178.

    Google Scholar 

  41. H. Nichols andW. Rostoker,Trans. ASM 56 (1963) 494.

    Google Scholar 

  42. M. Watkins, L. Johnson andN. N. Breyer, 4th Interamerican Conference on Materials Technology (Caracas, 1975) p. 31.

  43. L. P. Costas,Corrosion-N.A.C.E. 31 (1975) 91.

    Google Scholar 

  44. S. Dinda, andW. R. Warke,Mater. Sci. Eng. 24 (1976) 199.

    Google Scholar 

  45. C. M. Preece,Res. Dev. 23 (1972) 30.

    Google Scholar 

  46. H. Nichols andW. Rostoker,Trans. AIME 224 (1962) 1258.

    Google Scholar 

  47. M. D. Chadwick, R. B. Gibbon andD. Howel, IRD-64-55 and IRD-65-57.

  48. W. R. Goggin andJ. W. Moberly,Trans. ASM Qtly. 59 (1966) 315.

    Google Scholar 

  49. M. Aucouturier, P. Lacombe andC. Roquescarmes,Compt. Rendus 270C (1970) 469.

    Google Scholar 

  50. Idem, Mem. Sci. Rev. Met. 67 (1970) 367.

    Google Scholar 

  51. C. Brichet, L. Peeters, C. Roques-Carmes andG. Wyon,Compt. Rendus 271C (1970) 617.

    Google Scholar 

  52. L. Peeters, C. Roques-Carmes, M. Aucouturier andG. Wyon,Mem. Sci. Rev. Met. 69 (1972) 81.

    Google Scholar 

  53. D. J. Goddard andJ. A. Williams,J. Inst. Met. 99 (1971) 323.

    Google Scholar 

  54. K. J. Goddard andC. A. P. Horton,Metallography 6 (1973) 131.

    Google Scholar 

  55. C. Roques-Carmes, M. Aucouturier andP. Lacombe,Metal Sci. 7 (1973) 128.

    Google Scholar 

  56. S. K. Marya andG. Wyon,Scripta Met. 9 (1975) 1009.

    Google Scholar 

  57. Idem, Metallography 9 (1976) 123.

    Google Scholar 

  58. C. F. Old, AERE-R8343 (1976).

  59. F. N. Rhines, J. A. Alexander andW. F. Barclay,Trans. ASM 55 (1962) 22.

    Google Scholar 

  60. W. Rostoker, Armour Research Foundation Report B183 (1963).

  61. H. Ichinose,Trans. Jap. Inst. Met. 9 (1968) 35.

    Google Scholar 

  62. M. J. Malm andC. M. Preece,Mater. Sci. Eng. 11 (1973) 223.

    Google Scholar 

  63. G. Wesley-Austin,J. Inst. Met. 58 (1936) 173.

    Google Scholar 

  64. W. R. Smith andP. E. J. Forsyth,Metallurgia 34 (1946) 186, 245.

    Google Scholar 

  65. Y. M. Potak andI. M. Shchlegakov,Zhur Tekh Fiz 25 (1955) 897.

    Google Scholar 

  66. N. V. Pertsov andP. A. Rebinder,Dokl. Akad. Nauk USSR 123 (1958) 1068.

    Google Scholar 

  67. P. D. Novokreshehenov andN. V. Savchenko,Dokl Akad Nauk, Tekh Fiz 148 (1963) 328.

    Google Scholar 

  68. R. W. Vook, Conference on Environment Sensitive Mechanical Behaviour, edited by A. R. C. Westwood and N. S. Stoloff (Gordon and Breach, New York, 1966) p. 657.

    Google Scholar 

  69. R. Chadwick,J. Inst. Met. 97 (1969) 93.

    Google Scholar 

  70. K. Nagata andS. Seto, Sumitomo Light Metal Technical Reports,10 (1969) 21.

    Google Scholar 

  71. M. M. Shea andN. S. Stoloff,Mater. Sci. Eng. 12 (1973) 245.

    Google Scholar 

  72. R. Eborall andP. Gregory,J. Inst. Met. 84 (1955–6) 88.

    Google Scholar 

  73. W. H. Bassett,Proc. ASTM 18 (1918) 153.

    Google Scholar 

  74. C. H. Desch,J. Inst. Met. 22 (1919) 247.

    Google Scholar 

  75. H. Moore andS. Beckinsale,J. Inst. Met. 23 (1920) 225.

    Google Scholar 

  76. H. Moore, S. Beckinsale andC. E. Malinson,ibid. 25 (1921) 33.

    Google Scholar 

  77. D. Crampton,Trans. AIME 89 (1930) 23.

    Google Scholar 

  78. W. Lynes,Proc. ASTM 41 (1941) 859.

    Google Scholar 

  79. T. C. Wilson, G. Edmunds, E. A. Anderson andW. H. Pierce, Symposium on Stress Corrosion Cracking (ASTM-AIME, Philadelphia, 1944) 173.

    Google Scholar 

  80. W. D. Robertson,J. Metals (1951) 1190.

  81. W. D. Martin and G. C.Smith, private communication.

  82. T. L. Johnston, R. G. Davies andN. S. Stoloff,Phil. Mag. 12 (1965) 305.

    Google Scholar 

  83. G. Edmunds, Symposium on stress corrosion cracking of metals (ASTM-AIME, Philadelphia, 1944) p. 67.

    Google Scholar 

  84. I. B. Cadoff, E. Levine andH. T. Michels,Met. Trans. 3 (1972) 2139.

    Google Scholar 

  85. S. Seelinger andN. S. Stoloff, “In-situ composites”, Vol. II (Gordon and Breach, New York, 1973) p. 223.

    Google Scholar 

  86. T. M. Regan andN. S. Stoloff,Met. Trans. 8A (1977) 885.

    Google Scholar 

  87. J. H. S. Dickinson,J. Inst. Met. 24 (1920) 315.

    Google Scholar 

  88. H. J. Miller,ibid. 37 (1927) 183.

    Google Scholar 

  89. M. E. Whittaker,Metallurgia 39 (1948) 21.

    Google Scholar 

  90. V. I. Likhtman, E. D. Shchukin andP. A. Rebinder, “Physico-Chemical Mechanics of Metals” (Acad. Sci. USSR, Moscow, 1962).

    Google Scholar 

  91. H. F. Hartley,J. Inst. Met. 37 (1962) 193.

    Google Scholar 

  92. B. D. Summ,Phys. Metals Metallog. 14 (1963) 104.

    Google Scholar 

  93. N. I. Flegontova, B. D. Summ andYú V. Goryunov,ibid. 18 (1964) 85.

    Google Scholar 

  94. M. H. Kamdar andA. R. C. Westwood, US Government Research Reports40 (1965) AD 613701.

    Google Scholar 

  95. V. Y. Traskin,Fiz Khim Mekh Met 1 (1965) 645.

    Google Scholar 

  96. C. F. Old andP. Trevena, AERE-R8311 (1976).

  97. F. A. Shunk andW. R. Warke,Scripta Met. 8 (1974) 519.

    Google Scholar 

  98. V. N. Rozhanski, N. V. Pertsov, E. D. Shchukin andP. A. Rebinder,Dokl Akad Nauk USSR 116 (1957) 769.

    Google Scholar 

  99. G. S. Knishnik,Nauk Tr. Vses Zaoch Mashinostroit Inst. 12 (1975) 79.

    Google Scholar 

  100. E. D. Shchukin andV. I. Likhtman,Sov. Phys. Dokl 4 (1959) 111.

    Google Scholar 

  101. Yú V. Goryunova,Dokl Akad Nauk USSR 153 (1963) 634.

    Google Scholar 

  102. L. A. Kochanova, “The role of surface phenomena in metallurgy”, (Moscow Univ., 1963) p. 129.

  103. A. R. C. Westwood andM. H. Kamdar,Phil. Mag. 8 (1963) 787.

    Google Scholar 

  104. A. R. C. Westwood,ibid. 9 (1964) 199.

    Google Scholar 

  105. B. D. Summ, L. V. Ivanova andYú V. Goryunova,Fiz. Khim Mekhan Mat. 1 (1965) 648.

    Google Scholar 

  106. M. H. Kamdar andA. R. C. Westwood, “Environment Sensitive Mechanical Behaviour” (Gordon and Breach, New York, 1966) p. 581.

    Google Scholar 

  107. A. R. C. Westwood, “Strengthening mechanisms—metal and ceramics” (Syracuse University Press, 1966) p. 407.

  108. M. H. Kamdar andA. R. C. Westwood, International Conference on Strengths of Metals and Alloys (Jap. Inst. Metals, Sendai, 1968) p. 525.

    Google Scholar 

  109. Idem, US Government Research Reports68 (1968) AD 66866.

    Google Scholar 

  110. Idem, Acta. Met. 16 (1968) 1335.

    Google Scholar 

  111. A. H. Maitland andG. A. Chadwick,Phil. Mag. 19 (1969) 645.

    Google Scholar 

  112. M. H. Kamdar,Met. Trans. 2 (1971) 2937.

    Google Scholar 

  113. G. I. Denshehikova, Yú V. Goryunova, L. S. Soldatchenkova andB. D. Summ,Fiz. Khim Mekhan Mat. 11 (1975) 5.

    Google Scholar 

  114. N. J. E. Gunn, C. A. Stubbington andJ. T. Barlett, R. A. E. Tech. Memo Mat 233 (1975).

  115. W. T. Grubb andM. H. Morgan III, American Nuclear Society Topical Meeting on Reactor Fuel Performance (1977).

  116. E. G. Coleman, D. Weinstein andW. Rostoker,Acta, Met. 9 (1961) 491.

    Google Scholar 

  117. M. Tanaka andH. Fukunaga,J. Soc. Mater. Sci. (Jap.) 18 (1969) 411.

    Google Scholar 

  118. J. E. Cordwell, Proceedings of International Congress organised by the British Nuclear Energy Society, Nottingham (British Nuclear Energy Society, London, 1973) p. 177.

    Google Scholar 

  119. H. Schottky, K. Schiektel andR. Stolle,Arch Eisenhutten. 4 (1931) 541.

    Google Scholar 

  120. E. M. Kennedy Jr, Wadc TR 58–108 (1958) Astia 151075.

  121. A. Kelly, W. R. Tyson andA. H. Cottrell,Phil. Mag. 15 (1967) 567.

    Google Scholar 

  122. J. F. Hildebrand,Mater Protection and Performance 12 (1973) 35.

    Google Scholar 

  123. W. Radeker,Werkstoffe und Korrosion 24 (1973) 851.

    Google Scholar 

  124. J. C. Lynn, Ph. D. Thesis, I.I.T. (1974).

  125. N. N. Breyer andK. L. Johnson,J. Testing and Evaluation 2 (1974) 471.

    Google Scholar 

  126. S. M. Baranov andS. I. Karatushkin,Soviet Mater. Sci. 3 (1967) 101.

    Google Scholar 

  127. W. Herrnkind, 3rd International Conference on Lead (Venice, 1968) 387.

  128. W. Warke, K. L. Johnson ANDN. N. Breyer, “Corrosion by liquid metals” (Plenum Press, New York, 1970) p. 417.

    Google Scholar 

  129. W. Warke andN. N. Breyer,J. Iron Steel Inst. (1971) 779.

  130. H. W. Hayden andS. Floreen,Phil. Mag. 20 (1969) 135.

    Google Scholar 

  131. L. J. G. vanEwijk,J. Inst. Met. 56 (1935) 241.

    Google Scholar 

  132. W. E. Goodrich,J. Iron Steel Inst. 132 (1935) 63.

    Google Scholar 

  133. M. S. Wang, M. Sc. Thesis, Leeds (1943).

  134. R. Genders,J. Inst. Met. 37 (1927) 215.

    Google Scholar 

  135. G. F. Kosogov andV. I. Likhtman,Soviet Phys. Dokl. 5 (1960) 1054.

    Google Scholar 

  136. F. Page,Proc. Amer. Electroplaters Soc. (1943) 51.

  137. W. Radecker,Stahl und Eisen 73 (1973) 654.

    Google Scholar 

  138. M. Andreani, P. Azou andP. Bastien,C. R. Acad. Sci. Paris 263C (1966) 1041.

    Google Scholar 

  139. M. Andreani, P. Azou andO. Bastien,Mem. Sci. Rev. Met. 66 (1969) 21.

    Google Scholar 

  140. J. E. Cantwell andR. E. Bryant, Hydrocarbon Processing, May (1973) p. 114.

  141. A. H. Cottrell andP. R. Swann,Chem. Eng. (London) (1976) 266.

  142. V. L. Kolmogorov, V. A. Chichigin, V. G. Burdukovsky andB. A. Antoshechkin,Russ. Met. 1 (1976) 61.

    Google Scholar 

  143. R. R. Hough andR. Rolls,Scripta Met. 4 (1970) 17.

    Google Scholar 

  144. Idem, J. Mater. Sci. 6 (1971) 1493.

    Google Scholar 

  145. Idem, Scripta Met. 8 (1974) 39.

    Google Scholar 

  146. British Engine Technical Reports6 (1965) 76.

  147. Ibid. 7 (1966) 42.

  148. Ibid. 11 (1972) 63.

  149. J. G. Ball,Chem. Eng. (London) (1976) 275.

  150. W. M. Robertson,Trans. AIME 236 (1966) 1478.

    Google Scholar 

  151. M. J. Kelley andN. S. Stoloff,Met. Trans. A 6A (1975) 159.

    Google Scholar 

  152. S. P. Lynch, Proceedings of the 4th International Conference on Fracture,11 Vol. 2 (University of Waterloo Press, 1977) p. 859.

  153. V. M. Zalkin,Sov. Mater. Sci. 4 (1968) 18.

    Google Scholar 

  154. M. A. Krishtal,ibid. 5 (1969) 537.

    Google Scholar 

  155. E. D. Shchukin andV. S. Yushchenko,ibid. 2 (1966) 95.

    Google Scholar 

  156. C. M. Preece andA. R. C. Westwood,Trans. ASM 62 (1969) 418.

    Google Scholar 

  157. A. A. Griffith,Phil. Trans. Roy. Soc. 221A (1920) 163.

    Google Scholar 

  158. C. E. Inglis,Trans. Inst. Naval Architects 55 (1913) 219.

    Google Scholar 

  159. C. Zener, “Fracturing of Metals” (ASM, Metals Park, Ohio, 1943) p. 3.

    Google Scholar 

  160. N. J. Petch, “Fracture”, Proceedings of the Swampscott Conference, (1959) edited by B. L. Averbachet al. (John Wiley, New York, 1959) p. 54.

    Google Scholar 

  161. A. N. Stroh,Adv. Phys. 6 (1957) 418.

    Google Scholar 

  162. E. D. Hondros,Phil Mag. 29 (1974) 771.

    Google Scholar 

  163. M. I. Chaevskii,Sov. Mater. Sci. 1 (1965) 433.

    Google Scholar 

  164. M. I. Chaevskii andV. V. Popovich,ibid. 2 (1966) 102.

    Google Scholar 

  165. I. N. Toropovskaya,ibid. 6 (1970) 324.

    Google Scholar 

  166. A. S. Tetelman andS. Kunz, Technical Report Contract DAHC-04-69-C-0008, UCLA (1973).

  167. B. C. Edwards, H. E. Bishop, J. C. Riviere andB. L. Eyre, Aere R8298 (1976).

  168. E. Levine, H. Solomon andI. Cadoff,Acta. Met. 12 (1964) 119.

    Google Scholar 

  169. A. W. Thompson andI. M. Bernstein, 4th International Conference on Fracture, (University of Waterloo Press, 1977) p. 249.

  170. H. Allsop, RAE TR 77014.

  171. M. Barlow andP. J. Planting,Z. Metall 60 (1969) 817.

    Google Scholar 

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Nicholas, M.G., Old, C.F. Liquid metal embrittlement. J Mater Sci 14, 1–18 (1979). https://doi.org/10.1007/BF01028323

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