Abstract
Polyacrylonitrile (PAN), mixed with Co(II) or Fe(II) salts and high-area carbon and then heat treated, has been found to yield very promising catalysts for O2 reduction in concentrated alkaline and acid solutions. The catalytic activities are comparable to those for the heat-treated corresponding transition metal macrocycles and polypyrrole black-based catalysts. The addition of the transition metal to the nitrogen-containing polymer, either before or after the heat treatment with carbon, is an important factor for good activity. The nitrile nitrogen of the PAN is probably retained and converted to pyridyl nitrogen during the heat treatment, and this nitrogen is believed to provide binding sites for the transition metal ions, which then act as catalytic sites for oxygen reduction to peroxide and its decomposition.
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H. Jahnke, M. Schoenborn and G. Zimmermann,Topics in Current Chemistry 61 (1976) 133.
V. S. Bagotzky, M. R. Tarasevich, K. A. Radyushkina, O. A. Levina and S. I. Andrusova,J. Power Sources 2 (1977/78) 233.
J. A. R. van Veen, J. F. van Baar and K. J. Kroese,J. Chem. Soc., Faraday Trans. I 77 (1981) 2827.
K. Wiesener and G. Gruenig,J. Electroanal. Chem 180 (1984) 639.
I. Iliev, S. Gamburtsev, A. Kaisheva, A. Fuhrmann and K. Wiesener,J. Power Sources 13 (1984) 217.
D. Scherson, S. L. Gupta, C. Fierro, E. B. Yeager, M. E. Kordesch, J. Eldridge, R. W. Hoffman and J. Blue,Electrochim. Acta 28 (1983) 1205.
K. Okabayashi, O. Ikeda and H. Tamura,Chem. Lett. (1982) 1659.
D. Scherson, A. A. Tanaka, S. L. Gupta, D. Tryk, C. Fierro, R. Holze and E. B. Yeager,Electrochim. Acta 31 (1986) 1247.
K. A. Radyushkina and M. R. Tarasevich,Elektrokhimiya 22 (1986) 1155.
G. Gruenig, K. Wiesener, A. Kaisheva, S. Gamburtsev and I. Iliev,Elektrokhimiya 19 (1983) 1571.
S. L. Gupta, W. Aldred and E. B. Yeager, in ‘Extended Abstracts,’ Vol. 83-2, The Electrochemical Society, Pennington, NJ (1983) p. 626.
R. Holze, D. Scherson, D. Tryk, S. L. Gupta and E. Yeager, in ‘Extended Abstracts’, 35th Meeting of the International Society of Electrochemistry, Berkeley, CA (1984) p. 399.
J. McBreen, W. E. O'Grady, D. E. Sayers and C. Y. Yang, in ‘Extended Abstracts,’ Vol. 87-1, The Electrochemical Society, Pennington, NJ (1987) p. 746.
S. Gupta, D. Tryk, M. Daroux, W. Aldred and E. Yeager, in ‘Proceedings of the Symposium on Load Levelling and Energy Conservation in Industrial Processes, (edited by D. Chin), The Electrochemical Society, Pennington, NJ (1986) p. 207.
S. Gupta, D. Tryk, W. Aldred, I. Bae and E. Yeager, in ‘Extended Abstracts,’ Vol. 87-1, The Electrochemical Society, Pennington, NJ (1987) p. 455.
I. Bae, D. Tryk, S. Gupta and E. Yeager, manuscript in preparation.
E. Fitzer, K. Mueller and W. Schaefer, in ‘Chemistry and Physics of Carbon’ (edited by P. L. Walker Jr), Marcel Dekker, New York (1971) Vol. 7, pp. 237–383.
H. Teoh, P. D. Metz and W. G. Wilhelm,Mol. Cryst. Liq. Cryst. 83 (1982) 297 and references therein.
S. Clouser, Ph. D. Dissertation, Case Western Reserve University (1981) p. 58.
I. Bae, Case Western Reserve University, unpublished results.
E. Deltombe and M. Pourbaix, in ‘Atlas of Electrochemical Equilibria in Aqueous Solutions’ (edited by M. Pourbaix), Pergamon, Oxford (1966) pp. 322–329.
Yu. V. Pleskov and V. Yu. Filinovskii, ‘The Rotating Disc Electrode’, Consultants Bureau, New York (1976) pp. 90–92.
R. E. Carbonio, D. Tryk and E. Yeager, in ‘Proceedings of the Symposium on Electrode Materials and Processes for Energy Conversion and Storage’ (edited by S. Srinivasan, H. Wroblowa and S. Wagner), The Electrochemical Society, Pennington, NJ (1987) pp. 238–255.
M. S. Hossain, D. Tryk and E. Yeager, in ‘Extended Abstracts’, Vol. 87-1, The Electrochemical Society, Pennington, NJ (1987) p. 466.
H. Hinden and J. Gauger,J. Electrochem. Soc.,133 (1986) 692.
F. Solomon, private communication, May 1987.
M. P. Fuller and P. R. Griffiths,Anal. Chem. 50 (1978) 1906.
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Gupta, S., Tryk, D., Bae, I. et al. Heat-treated polyacrylonitrile-based catalysts for oxygen electroreduction. J Appl Electrochem 19, 19–27 (1989). https://doi.org/10.1007/BF01039385
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DOI: https://doi.org/10.1007/BF01039385