Conclusion and extensions
We hope that this Review has made readers more aware of solvation of inorganic complexes, and of the importance of such knowledge in understanding their chemistryperhaps particularly their reactivity. The approach just set out for inorganic complexes should be of considerable value in the field or organometallic chemistry. In particular, informed use of solvation characteristics should help in optimising conditions for organometallic reactions and in homogeneous catalysis. Unfortunately, solvation data on reactants are too sparse (the subject index ofComprehensive Organometallic Chemistry contains justthree entries under “solubility”!) for serious examination of reactivity trends in terms of initial state and transition state contributions to be possible in almost all areas. Moreover, there are some fundamental problems over transfer parameters. Thus, a favourite electrochemical assumption is that the ferrocene/ferrocinium redox potential is independent of solvent. Yet, the dependence of rate constants on medium for outer-sphere electron transfer in the ferrocene/ferrocinium system can only be understood(66) in terms of specific solvation effects which are incompatible with the parallel solvation changes of these two substrates implicit in the redox potential assumption. The solvation of organometallic species should prove a most rewarding area for continued study, but it will be some time before the overall picture becomes as clear as in the more limited area of classical transition metal complexes considered in the present Review.
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References
M. J. Blandamer and J. Burgess,Educ. Chem.,24, 85 (1987).
H. D. B. Jenkins and K. F. Pratt,Adv. Inorg. Chem. Radiochem.,22, 1 (1978).
E.g., R. Alexander, A. J. Parker, J. H. Sharp, and W. E. Waghorne,J. Am. Chem. Soc.,94, 1148 (1972); B. E. Conway,J. Soln. Chem.,7, 721 (1978); Y. Marcus,Pure Appl. Chem.,55, 977 (1983); Y. Marcus,Ion Solvation, Wiley, 1986.
R. D. Shannon and C. T. Prewitt,Acta Cryst.,B25, 925 (1969);Idem,B26, 1046 (1970); M. J. Blandamer and M. C. R. Symons,J. Phys. Chem.,67, 1304 (1963).
M. H. Abraham,J. Chem. Soc., Faraday Trans. I.,69, 1375 (1973); S. Villermaux and J.-J. Delpuech,Bull. Soc. Chim. Fr. A, 2534 (1974).
E. Grunwald, G. Baughman, and G. Kohnstam,J. Am. Chem. Soc.,82, 5801 (1960); A. J. Parker and R. Alexander,J. Am. Chem. Soc.,89, 5549 (1967).
J. F. Coetzee and W. R. Sharpe,J. Phys. Chem.,75, 3141 (1971); M. Booij and G. Somsen,Electrochim. Acta,28, 1883 (1983); J. I. Kim and E. A. Gomaa,Bull. Soc. Chem. Belg.,90, 391 (1981); J. I. Kim,Bull. Soc. Chim. Belg.,95, 435 (1986).
M. H. Abraham, T. Hill, H. C. Ling, R. A. Shultz, and R. A. C. Watt,J. Chem. Soc., Faraday Trans. I.,80, 489 (1984).
O. Povovych,Analyt. Chem.,38, 558 (1966); O. Popovych and A. J. Dill,Analyt. Chem.,41, 456 (1969); O. Popovych,Crit. Rev. Analyt. Chem.,1, 73 (1970).
J. C. Jayne and E. L. King,J. Am. Chem. Soc.,86, 3989 (1964); D. W. Kemp and E. L. King,J. Am. Chem. Soc.,89, 3433 (1967); L. P. Scott, T. J. Weeks, D. J. Bracken, and E. L. King,J. Am. Chem. Soc.,91, 5219 (1969).
M. J. Blandamer and J. Burgess,Inorg. Chim. Acta,64, L113 (1982);J. Chem. Soc., Dalton Trans., 867 (1985); D. Sengupta, A. Pal, and S. C. Lahiri,J. Chem. Soc., Dalton Trans., 868 (1985).
M. J. Blandamer, J. Burgess, B. Clark, D. Elvidge, A. W. Hakin, P. Guardado, and C. D. Hubbard,J. Chem. Soc., Faraday Trans. I., accepted for publication.
J. F. Coetzee and W. K. Istone,Analyt. Chem.,52, 53 (1980); A. Lewandowski,Electrochim. Acta,29, 547 (1984);Idem.,31, 59 (1986).
M. J. Blandamer, J. Burgess, B. Clark, P. P. Duce, A. W. Hakin, N. Gosal, S. Radulovic, P. Guardado, F. Sanchez, C. D. Hubbard, and E. A. Abu-Gharib,J. Chem. Soc., Faraday Trans. I.,82, 1471 (1986).
M. J. Blandamer, J. Burgess, P. P. Duce, N. Gosal, R. Sherry, P. Guardado, and F. Sanchez,Transition Met. Chem.,9, 3 (1984).
S.-I. Ishiguro and H. Ohtaki,J. Coord. Chem.,15, 237 (1987).
J. Burgess and J. Kijowski,Adv. Inorg. Chem. Radiochem.,24, 57 (1981).
M. J. Blandamer, J. Burgess, and J. Kijowski,Inorg. Chem. Acta,58, 155 (1982).
J. Burgess and E. A. Abu-Gharib,J. Chem. Res., (S), 8, (M) 0201.
M. J. Blandamer, J. Burgess, S. J. Hamshere, C. White, R. I. Haines, and A. McAuley,Can. J. Chem.,61, 1361 (1983).
J. Burgess, R. D. Peacock, and J. H. Rogers,J. Fluorine Chem.,19, 333 (1982).
M. J. Blandamer, J. Burgess, and E. A. Abu-Gharib,Transition Met. Chem.,9, 193 (1984).
W. L. Reynolds, M. Glavas, and E. Dzeliliovic,Inorg. Chem.,22, 1946 (1983).
J. Burgess, S. Radulovic, and F. Sanchez,Transition Met. Chem., in press, (TMC 1755).
F. M. van Meter and H. M. Neumann,J. Am. Chem. Soc.,98, 1382 (1976).
E. A. Abu-Gharib, M. J. Blandamer, J. Burgess, N. Gosal, P. Guardado, F. Sanchez, and C. D. Hubbard,Transition Met. Chem.,9, 306 (1984).
J. Burgess,J. Chem. Soc. A, 2728 (1968).
J. Burgess and C. D. Hubbard,J. Chem. Soc., Chem. Comm., 1482 (1983).
M. J. Blandamer, J. Burgess, J. Fawcett, S. Radulovic, and D. r. Russell,Transition Met. Chem., accepted (TMC 1816).
A. Al Alousy and J. Burgess,Transition Met. Chem., in press, (TMC 1776).
M. J. Blandamer, J. Burgess, J. G. Chambers, and A. J. Duffield,Transition Met. Chem.,6, 156 (1981).
M. J. Blandamer, J. Burgess, and T. Digman,Transition Met. Chem.,10, 274 (1985).
R. bin Ali and J. Burgess, unpublished observations.
F. Basolo,Coord. Chem. Rev.,3, 213 (1968).
A. G. Sykes and J. A. Weil,Progr. Inorg. Chem.,13, 1 (1970); M. Hancock, B. Nielsen, and J. Springborg,Inorg. Synth.,24, 220 (1986).
A. J. Leo, C. Hansch,and D. Elkins,Chem. Rev.,71, 525 (1971).
E. g., A. I. Shkadova,Farm, Zh. (Kiev),24, 39 (1969); P. Rohdewald,Pharm. Z.,38, 1342 (1971); A. Burger,Pharm. Ind.,35, 626 (1973); J. W. Mauger, H. Petersen, K. S. Alexander, and A. N. Paruta,Drug Dev. Ind. Pharm.,3, 163 (1977).
M. J. Clarke and L. Podbielski,Coord. Chem. Rev.,78, 253 (1987) {see,e.g., pp. 269, 273, 277, 287, 292, 304}; A. G. Jones, A. Davison, J. Kronauge, and M. J. Abrams,Chem. Abs.,107, 92826c (1987).
K. Burger,Solvation, Ionic and Complex Formation Reactions in Non-aqueous Solvents, Elsevier, 1983.
S. Ahrland,Pure Appl. Chem.,54, 1451 (1982).
K. Bridger, R. C. Patel, and E. Matijevic,J. Phys. Chem.,87, 1192 (1983).
H. Doe and T. Kitagawa,Inorg. Chem.,21, 2272 (1982).
P. G. David,Polyhedron,4, 437 (1985).
C. Amuli, M. Elleb, J. Meullemeestre, M. J. Schwing, and F. Vierling,Inorg. Chem.,25, 856 (1986).
Y. Sasaki, K. Abe, and M. Takizawa,Bull. Chem. Soc. Jpn.,58, 1049 (1985).
Z. A. Saprykova and N. D. Chichirova,Russ. J. Inorg. Chem.,30, 527 (1985).
D. M. Muir, P. Singh, C. C. Kenna, N. Tsuchida, and M. D. Benari,Aust. J. Chem.,38, 1079 (1985).
C. K. Ingold,Structure and Mechanism in Organic Chemistry, Cornell University Press, 1953.
A. J. Parker,Chem. Rev.,61, 1 (1969).
M. J. Blandamer and J. Burgess,Coord. Chem. Rev.,31, 93 (1980);Pure Appl. Chem.,51, 2087 (1979);Idem.,54, 2285 (1982);Idem.,55, 55 (1983).
E. Tommila and I. Palenius,Acta Chem. Scand.,17, 1980 (1963).
E. M. Woolley and L. G. Hepler,Analyt. Chem.,44, 1520 (1972); B. G. Cox, R. Natarajan, and W. E. Waghorne,J. Chem. Soc., Faraday Trans. I,75, 1780 (1979).
D. W. Margerum and L. P. Morgenthaler,J. Am. Chem. Soc.,84, 706 (1962).
M. J. Blandamer, J. Burgess, and D. L. Roberts,J. Chem. Soc., Dalton Trans., 1086 (1978).
F. M. van Meter and H. M. Neumann,J. Am. Chem. Soc.,98, 1388 (1976).
M. J. Blandamer, J. Burgess, S. D. Cope, and T. Digman,Transition Met. Chem.,9, 347 (1984).
Seee.g., C. F. Wells,J. Chem. Soc., Faraday Trans. I,73, 1851 (1977); J. Burgess and M. G. Price,J. Chem. Soc. A, 3108 (1971); and refs. therein.
J. Bjerrum, A. W. Adamson, and O. Bostrup,Acta Chem. Scand.,10, 329 (1956).
J. Burgess,Spectrochim. Acta,26A, 1369 (1970).
H. Saito, J. Fujita, and K. Saito,Bull. Chem. Soc. Jpn.,41, 863 (1968).
A. Werner and A. Miolati,Z. Phys. Chem.,14, 506 (1894); A. Werner and R. Klein,Z. Anorg. Allg. Chem.,22, 111 (1899); A. Werner and C. Herty,Z. Phys. Chem.,38, 331 (1901).
A. Indelli and R. Zamboni,J. Chem. Soc., Faraday Trans. I,68, 1831 (1972); F. Kawaizumi, F. Nakao, and H. Nomura,J. Soln. Chem.,14, 688 (1985); J. K. Hovey and P. R. Tremaine,J. Phys. Chem.,89, 5541 (1985); K. Yoshitani,Bull. Chem. Soc. Jpn.,58, 1646 (1985); F. Kawaizumi, H. Nomura, and F. Nakao,J. Soln. Chem.,16, 133 (1987).
E.g., K. Kurotaki and S. Kawamura,J. Chem. Soc., Faraday Trans. I,77, 217 (1981).
R. van Eldik,Angew. Chem. Int. Edn. Engl.,25, 673 (1986); M. Kotowski and R. van Eldik, inInorganic High Pressure Chemistry—Kinetics and Mechanisms, Ed. R. van Eldik, Elsevier, 1986, Chap. 4 (seee.g., pp. 241–3).
K. Mizutani and M. Yasuda,Bull. Chem. Soc. Jpn.,55, 1317 (1982).
E. S. Yang, M.-S. Chan, and A. C. Wahl,J. Phys. Chem.,84, 3094 (1980).
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Blandamer, M.J., Burgess, J. Solvation of transition metal complexes: thermochemical approaches. Transition Met Chem 13, 1–18 (1988). https://doi.org/10.1007/BF01041490
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DOI: https://doi.org/10.1007/BF01041490