Summary
2-Aminoacetophenone-2-thenoylhydrazone, Haath, C4H3SC(O)NHN=C(Me)C6H4NH2-o, forms complexes with metal(II) salts of empirical compositions [VO(Haath)2SO4], [M(Haath)2Cl2] [M=CoII, NiII, CuII or ZnII] and [M(aath)2] [M=VIVO, CoII, NiII, CuII or ZnII] which have been characterized by elemental analyses, molar conductance, magnetic susceptibility, electronic, e.s.r., i.r. and n.m.r. (1H and13C) spectral studies. X-ray and electron diffraction patterns have been obtained in order to elucidate the structure of the CuII complexes. Photoacoustic spectra of powder NiII complexes have been recorded and interpreted in the light of u.v./vis. spectra.
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References
B. Singh, R. N. Singh and R. C. Aggarwal,Ind. J. Chem.,23A, 480 (1984).
B. Singh, R. N. Singh and R. C. Aggarwal,Polyhedron,4, 401 (1985).
A. I. Vogel,A. Text Book of Qaantitative Inorganic Analysis, Longmans, London, 1969.
B. Singh, A. K. Srivastav and P. Srivastava,Transition Met. Chem.,13, 463 (1988).
L. V. Zzaroff and M. J. Buerger,The Power Method in X-ray Crystallography, McGraw Hill, New York, 119 (1958).
W. J. Geary,Coord. Chem. Rev.,7, 81 (1971).
B. N. Figgis and J. Lewis,Prog. Inorg. Chem.,6, 192 (1964).
D. L. Williams, D. W. Smith and S. C. Stoufer,Inorg. Chem.,6, 590 (1967).
F. A. Cotton and G. Wilkinson,Advanced Inorganic Chemistry, Wiley Interscience, New York, 1976, 849–916.
R. W. Mathews and R. A. Walton,Inorg. Chem.,10, 1433 (1971).
A. B. P. Lever,Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1968.
L. Sacconi,Transition Met. Chem.,4, 199 (1969).
C. K. Jørgensen,Acta Chem. Scand.,9, 1362 (1955).
C. J. Ballhausen and H. B. Gray,Inorg. Chem.,1, 111 (1962).
R. L. Farmer and F. L. Urbach,Inorg. Chem.,13, 587 (1974).
H. J. Stoklosa, J. B. Wasson and B. J. McCormick,Inorg. Chem.,13, 592 (1974).
A. Rosencwaig,Photoacoustics and Photoacoustic Spectroscopy, Wiley 1980.
R. Singh and R. S. S. Rao,J. Mol. Struct.,71, 23 (1981).
B. A. Goodman and J. B. Raynor,Adv. Inorg. Chem. Radiochem.,13, 135 (1970).
B. J. Hathaway and D. E. Billing,Coord. Chem. Rev.,5, 143 (1970).
I. Rani, K. B. Pandeya and R. P. Singh,Ind. J. Chem.,21A, 502 (1982).
H. Kon and N. E. Sharpless,J. Chem. Phys.,42, 906 (1965).
R. C. Aggarwal and K. K. Narang,Inorg. Chim. Acta. 7, 651 (1973).
C. N. R. Rao,Chemical Applications of Infrared Spectroscopy, Academic Press, New York, 1970, p. 258, 265.
J. Selbin, L. H. Holmes Jr and S. P. McGlynn,J. Inorg. Nucl. Chem.,25, 1359 (1963).
C. J. O'Conner,Prog. Inorg. Chem. 29, 231 (1982).
O. Noboru and K. Nakamoto,Inorg. Chem.,10, 798 (1975).
R. J. H. Clark,J. Chem. Soc., 1377 (1963).
R. M. Silverstein, L. C. Bassless and T. Morril,Spectrometric identification of Organic Compounds, Wiley, New York, 1981, 249.
S. E. Livingstone,Coord. Chem. Rev.,7, 77 (1971).
M. Sakamoto,Inorg. Chim. Acta. 131, (1967).
D. T. Haworth, D. L. Mass and M. Das,J. Inorg. Nucl. Chem.,43, 1807 (1981).
P. Domiano C. Pelizzi, G. Predieri, C. Vignali and G. Palla,Polyhedron,3, 281 (1984).
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Singh, B., Srivastav, A.K. 2-Aminoacetophenone-2-thenoylhydrazone complexes of bivalent 3d metal ions. Transition Met Chem 14, 415–419 (1989). https://doi.org/10.1007/BF01092581
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DOI: https://doi.org/10.1007/BF01092581