Abstract
A fairly complete but limited set of gas phase reactions involving nitrogen-bearing molecules is linked to a simple model of grain surface reactions. Calculations are performed attempting to simulate the nitrogen chemistry in interstellar clouds of low and high density. While it appears probable that grain surface reactions contribute to the chemistry in both régimes, conclusive evidence awaits observational and theoretical developments.
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Adams, N. G. and Smith, D.: 1976,J. Phys. B 9, 1439.
Allen, M. and Robinson, G. W.: 1977,Astrophys. J. 212, 396.
Bar-Nun, A.: 1975,Astrophys. J. 197, 341.
Barrett, A. H., Ho, P. T. P. and Myers, P. C.: 1977,Astrophys. J. 211, L39.
Barsuhn, J. and Walmsley, C. M.: 1977,Astron. Astrophys. 54, 345.
Baulch, D. L., Drysdale, D. D., Horne, D. G. and Lloyd, A. C.: 1969,High Temperature Reaction Rate Data, No. 4, Leeds University.
Biondi, M. A.: 1969,Can. J. Chem. 47, 1711.
Black, J. H. and Dalgarno, A.: 1977,Astrophys. J. (in press).
Bohme, D. K., Hemsworth, R. S., Rundle, H. W. and Schiff, H. I.: 1973,J. Chem. Phys. 58, 3504.
Bottcher, C.: 1976,J. Phys. B 9, 2899.
Breuer, H. D.: 1973, in Gordon and Snyder (eds),Molecules in the Galactic Environment, p. 381, John Wiley & Sons.
Crutcher, R. M. and Watson, W. D.: 1976,Astrophys. J. 209, 778.
Dalgarno, A.: 1976, in Avrett (ed.),Frontier of Astrophysics, p. 352, Harvard University Press.
Dalgarno, A. and Black, J. H.: 1976,Rep. Prog. Phys. 39, 573.
Fehsenfeld, F. C.: 1976,Astrophys. J. 209, 638.
Fehsenfeld, F. C. and Ferguson, E. E.: 1972,J. Chem. Phys. 56, 3066.
Fehsenfeld, F. C., Lindinger, W., Schmeltekopf, A. L., Albritton, D. L. and Ferguson, E. E. 1975,J. Chem. Phys. 62, 2001.
Fehsenfeld, F. C., Schmeltekopf, A. L. and Ferguson, E. E.: 1967,J. Chem. Phys. 46, 2802.
Field, G. B. and Steigman, G.: 1971,Astrophys. J. 166, 59.
Giguere, P. T. and Clark, F. O.: 1975,Astrophys. J. 198, 761.
Herbig, G. H.: 1968,Z. Astrophys. 68, 243.
Herbst, E. and Klemperer, W.: 1973,Astrophys. J. 185, 505.
Herbst, E., Bohm, D. K., Payzant, J. D. and Schiff, H. I.: 1975,Astrophys. J. 201, 603.
Hollenbach, D. J., Werner, M. W. and Salpeter, E. E.: 1971,Astrophys. J. 163, 165.
Hudson, R. D.: 1971,Rev. Geophys. Space Phys. 9, 305.
Huntress, W. T. and Anicich, V. G.: 1976,Astrophys. J. 208, 237.
Huntress, W. T., Kim, J. K. and Theard, L. P.: 1974,Chem. Phys. Letters 29, 189.
Iguchi, T.: 1975,Publ. Astron. Soc. Japan 27, 515.
Jenkins, E. B., Drake, J. F., Morton, D. C., Rogerson, J. B., Spitzer, L. and York, D. G.: 1973,Astrophys. J. 181, L122.
Jong, T. de: 1972,Astron. Astrophys. 20, 263.
Kaifu, N., Morris, M., Palmer, P. and Zuckerman, B.: 1975,Astrophys. J. 201, 98.
Kerr, J. A.: 1973, in Kochi (ed.),Free Radicals, II, Wiley, Interscience.
Kim, J. K., Theard, L. P. and Huntress, W. T.: 1975,J. Chem. Phys. 62, 45.
Knapp, G. R. and Jura, M.: 1976,Astrophys. J. 209, 782.
Langer, W.: 1976,Astrophys. J. 206, 699.
Leu, M. T., Biondi, M. A. and Johnson, R.: 1973a,Phys. Rev. A8, 413.
Leu, M. T., Biondi, M. A. and Johnson, R.: 1973b,Phys. Rev. A8, 420.
Leung, C. M. and Liszt, H. S.: 1976,Astrophys. J. 208, 732.
Lindinger, W., Albritton, D. L., and Fehsenfeld, F. C.: 1975,J. Chem. Phys. 62, 4957.
Lotz, W.: 1967,Astrophys. J. Suppl. 14, 207.
Millar, T. J. and Williams, D. A.: 1975,Monthly Notices Roy. Astron. Soc. 170, 51P.
Morton, D. C.: 1974,Astrophys. J. 193, L35.
Oppenheimer, M. and Dalgarno, A.: 1974,Astrophys. J. 192, 29.
Oppenheimer, M. and Dalgarno, A.: 1975,Astrophys. J. 200, 419.
Pickles, J. B. and Williams, D. A.: 1977,Astrophys. Space Sci. 52, 443 (Paper I).
Savage, B. D.: 1975,Astrophys. J. 199, 92.
Schiff, H. I., Hemsworth, R. S., Payzant, J. D. and Bohme, D. K.: 1974,Astrophys. J. 191, L49.
Snow, T. P.: 1975,Astrophys. J. 201, L21.
Solomon, P. M.: 1973,Phys. Today 26, 32.
Spitzer, L. and Jenkins, E. B.: 1975,Ann. Rev. Astron. Astrophys. 13, 133.
Stief, L. J., Donn, B., Glicker, S., Gentieu, E. P. and Mentall, J. E.: 1972a,Astrophys. J. 171, 21.
Stief, L. J.: 1972b,Mol. Photochem. 4, 153.
Turner, B. E. and Gammon, R. H.: 1975,Astrophys. J. 198, 71.
Turner, B. E. and Thaddeus, P.: 1977,Astrophys. J. 211, 755.
Viala, Y. P. and Walmsley, C. M.: 1976,Astron. Astrophys. 50, 1.
Watson, W. D.: 1973,Astrophys. J. 183, L17.
Watson, W. D.: 1974, in Balian, Encrenaz and Lequeux (eds),Atomic and Molecular Physics and the Interstellar Matter, p. 177, North Holland.
Whitworth, A. P.: 1975,Astrophys. Space Sci. 34, 155.
Zuckerman, B. and Turner, B. E.: 1975,Astrophys. J. 197, 123.
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Pickles, J.B., Williams, D.A. The chemistry of interstellar nitrogen. Astrophys Space Sci 52, 453–478 (1977). https://doi.org/10.1007/BF01093880
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DOI: https://doi.org/10.1007/BF01093880