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Participation of Cu(III) in copper sulfate-catalyzed oxidation of 3-carboxypropyl radicals with S2O8 2− ions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A mechanism was proposed for the selective oxidative cyclization of 3-carboxyprqpyl radicals to γ-butyrolactone when using the Na2S2O8-CuSO4 oxidation system. In this mechanism the Cu(III) ions take part in the reaction.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    Yu. N. Ogibin, É. I. Troyanskii, E. K. Starostin, S. I. Moryasheva & G. I. Nikishin

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  1. Yu. N. Ogibin
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  2. É. I. Troyanskii
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  3. E. K. Starostin
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  4. S. I. Moryasheva
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  5. G. I. Nikishin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 933–936, April, 1977.

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Ogibin, Y.N., Troyanskii, É.I., Starostin, E.K. et al. Participation of Cu(III) in copper sulfate-catalyzed oxidation of 3-carboxypropyl radicals with S2O8 2− ions. Russ Chem Bull 26, 859–862 (1977). https://doi.org/10.1007/BF01108221

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  • DOI: https://doi.org/10.1007/BF01108221

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