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Complexes of palladium, platinum and rhodium with 2,2′-biquinoline and 2-(2′-pyridyl)quinoline

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Summary

The reactions of 2,2′-biquinoline(biq) with M(PhCN)2X2 (M=Pd; X=Cl or Br; M=Pt, X=Cl, Br or I), K2PtCl4 and RhCl3·3H2O and of 2-(2′-pyridyl)quinoline (pq) with K2PtCl4 and RhCl3·3H2O have been investigated. The isolated complexescis-[Pd(biq)X2] (X=Cl or Br),cis-[Pt(biq)Cl2],cis-[Pt(biq)Cl2]·H2O,trans-[Pt(biq)2Br2]·5H2O, [Pt3(biq)2I6],mer-[Rh(biq)Cl3-(H2O)] andmer-[Rh(pq)Cl3(H2O)] have been characterized by elemental analyses, conductivity measurements, i.r., electronic, and1H n.m.r. spectra. The reaction of pq with K2PtCl4 in 1M H2SO4 gave the salt 2-(2′-pyridyl) quinolinium tetrachloroplatinate(II) pentahydrate, (pqH)2[PtCl4]·5H2O; when the reaction was carried out in aqueous acetone,cis-[Pt(pq)Cl2] was obtained. A new method for the synthesis ofcis-[Rh(biq)2X2]X (X=Cl or Br) is described; both compounds have been further characterized by1H n.m.r.

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References

  1. C. M. Harris and S. E. Livingstone,Rev. Pure Appl. Chem.,12, 16 (1962) and refs. therein,

    Google Scholar 

  2. E. Bielli, P. M. Gidney, R. G. Gillard and B. T. Heaton,J. Chem. Soc., Dalton Trans., 2133 (1974), and refs. therein.

  3. P. M. Kiernan and A. Ludi,J. Chem. Soc., Dalton Trans., 1127 (1978);

  4. Q. Jaradat, K. Barqawi and T. S. Akasheh,Inorg. Chim. Acta,116, 63 (1986).

    Google Scholar 

  5. M. H. Zaghal and H. A. Qaseer,Inorg. Chim. Acta,163, 193 (1989) and refs. therein.

    Google Scholar 

  6. V. Kumar, M. M. Haq and N. Ahmad,Indian J. Chem., Part A,17, 305 (1979).

    Google Scholar 

  7. G. R. Newkome and V. K. Gupta,Inorg. Chim. Acta,65, L165 (1982).

    Google Scholar 

  8. P. M. Gidney, R. D. Gillard and B. T. Heaton,J. Chem. Soc., Dalton Trans., 2621 (1972). and refs. therein,

  9. B. R. Ramesh, B. S. S. Mallikarjuna and G. K. N. Reddy,Nat. Acad. Sci. Lett.,1, 24 (1978), and refs. therein.

    Google Scholar 

  10. G. Zassinovich, A. Camus and G. Mestroni,Inorg. Nucl. Chem. Lett.,13, 865 (1976);

    Google Scholar 

  11. G. K. N. Reddy, R. Halesha, E. G. Leelamani and N. M. N. Gowda,Proc. Indian Natl. Sci. Acad., Part A,52, 1013 (1986).

    Google Scholar 

  12. F. R. Hartley,Organomet. Chem. Rev., Part A,6, 119 (1970), and refs. therein,

    Google Scholar 

  13. M. J. Church and M. J. Mays,J. Inorg. Nucl. Chem.,33, 253 (1971).

    Google Scholar 

  14. C. D. Tait, D. B. MacQueen, R. J. Donohoe, M. K. DeArmond, K. W. Hanck and D. W. Wertz,J. Phys. Chem.,90, 1766 (1986), and refs. therein.

    Google Scholar 

  15. L. J. Bellamy,The Infrared Spectra of Complex Molecules, 3rd Edit., Chapman and Hall, London, 1975,

    Google Scholar 

  16. N. B. Colthup, L. H. Daly and S. E. Wiberley,Introduction to Infrared and Raman Spectroscopy, 2nd Edit., Academic Press, New York, 1975.

    Google Scholar 

  17. K. Folting and L. L. Merritt Jr.,Acta Crystallogr.,B33, 3540 (1977).

    Google Scholar 

  18. R. J. Charlton, C. M. Harris, H. Patil and N. C. Stephenson,Inorg. Nucl. Chem. Lett.,2, 409 (1966).

    Google Scholar 

  19. G. H. Faye,Can. J. Chem.,44, 2729 (1966);

    Google Scholar 

  20. A. Seminara, A. Musumeci and A. Chisari,Inorg. Chim. Acta,82, 173 (1984).

    Google Scholar 

  21. K. Nakamoto,Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd Edit., Wiley, New York, 1978.

    Google Scholar 

  22. D. M. Klassen,Inorg. Chem.,15, 3166 (1976).

    Google Scholar 

  23. R. E. DeSimone and R. S. Drago,Inorg. Chem.,8, 2517 (1969).

    Google Scholar 

  24. J. A. G. Drake and D. W. Jones,Org. Mag. Reson.,18, 42 (1982).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Yarmouk University, Irbid, Jordan

    Mukarram H. Zaghal & Hanan A. Qaseer

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  1. Mukarram H. Zaghal
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  2. Hanan A. Qaseer
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Zaghal, M.H., Qaseer, H.A. Complexes of palladium, platinum and rhodium with 2,2′-biquinoline and 2-(2′-pyridyl)quinoline. Transition Met Chem 16, 39–44 (1991). https://doi.org/10.1007/BF01127868

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  • DOI: https://doi.org/10.1007/BF01127868

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