Skip to main content
SpringerLink
Log in

Organosilicon compounds having hydrocarbon bridges between silicon atoms

Communication 7. Structure of condensation products

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    With the aid of infrared spectra the structure of the fundamental structural unit was established for catalyticpolycondensation products obtained from α,ω-bistrimethylsilylalkanes and also for polymers obtained by the thermal polymerization of 1,1-dimethylsilacyclobutane and the catalytic polymerization of 1,1-dimethylsilacyclopentane.

  2. 2.

    Under the action of aluminum halides, p-bis(trimethylsilylmethyl)benzene and p-bistrimethylsilylbenzene react with liberation of tetramethylsilane and formation of sila-hydrocarbon condensation products. The latter contain alternations of silicon atoms and p-phenylenedimethylene or p-phenylene fragments in the chain.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. V. M. Vdovin, K. S. Pushchevaya, and A. D. Petrov, Izv. AN SSSR. Otd. khim. n. 281 (1961).

  2. V. M. Vdovin, K. S. Pushchevaya, and A. D. Petrov, Izv. AN SSSR. Otd. khim. n. 1275 (1961).

  3. V. M. Vdovin, K. S. Pushchevaya, N. A. Belikova, R. Sultanov, A. F. Platé and A. D. Petrov, Dokl. AN SSSR136, 96 (1961).

    Google Scholar 

  4. V. M. Vdovin, K. S. Pushchevaya, and A. D. Petrov, Dokl. AN SSSR141, 843 (1961).

    Google Scholar 

  5. Yu. P. Egorov, Dissertation, MGU (1957).

  6. S. G. Durgar'yan, Yu. P. Egorov, N. S. Nametkin, and A. V. Topchiev, Zh. obshch. khimii30, 2600 (1960).

    Google Scholar 

  7. J. K. Brown, N. Scheppard, and D. Simpson, Trans. Roy. Soc. [London] A247, 35 (1954).

    Google Scholar 

  8. H. Primas and H. H. Gunthard, J. Phys. et Rad.15, 209 (1954).

    Google Scholar 

  9. V. M. Vdovin and A. D. Petrov, Zh. obshch. khimii80, 838 (1960).

    Google Scholar 

  10. Yu. P. Egorov and E. D. Lubuzh, Dokl. AN SSSR136, 342 (1961).

    Google Scholar 

  11. J. W. Curry, J. Amer. Chem. Soc.78, 1686 (1956).

    Google Scholar 

  12. J. W. Curry, J. Organ. Chem. 1308 (1961).

  13. Application of Spectroscopy in Chemistry, edited by West [Russian translation], IL, p. 287 (1959).

  14. R. Glenn, Wilson, G. M. Hutzel, and A. G. Smith, J. Organ. Chem.24, 381 (1959); R. Glenn, Wilson, and G. M. Hutzel, ibid.24, 1791 (1959).

    Google Scholar 

  15. I. N. Nazarov and A. V. Semenovskii, Izv. AN SSSR. Otd. khim. n. 100 (1957).

  16. A. D. Petrov and G. I. Nikishin, Izv. AN SSSR. Otd. khim. n. 243 (1956).

  17. J. H. Sommer and J. R. Ansal, J. Amer. Chem. Soc.77, 2482 (1955).

    Google Scholar 

  18. R. West and E. G. Rochow, J. Organ. Chem.18, 1739 (1953).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    Yu. P. Egorov, K. S. Pushchevaya, E. D. Lubuzh, V. M. Vdovin & A. D. Petrov

Authors
  1. Yu. P. Egorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. S. Pushchevaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. D. Lubuzh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. M. Vdovin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. D. Petrov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Egorov, Y.P., Pushchevaya, K.S., Lubuzh, E.D. et al. Organosilicon compounds having hydrocarbon bridges between silicon atoms. Russ Chem Bull 12, 743–750 (1963). https://doi.org/10.1007/BF01134717

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01134717

Keywords

Search

Navigation