Conclusions
-
1.
The heats of combustion and standard heats of formation of tributyl and tripropyl phosphate, the butyl ester of dibutylphosphinic acid, and tributylphosphine oxide were determined.
-
2.
A linear dependence of the standard heat of formation on the empirical parameter Σσ and the molecular weight was established in the series tributylphosphine oxide-tributyl phosphate and triethyl phosphate-tributyl phosphate.
-
3.
The standard heats of formation of trimethyl and triamyl phosphate and the dibutyl ester of butylphosphinic acid were calculated.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
A. F. Bedford and C. T. Mortimer, J. Chem. Soc.,1960, 1622.
C. L. Chemic, C. T. Mortimer, and H. A. Skinner, J. Chem. Soc.,1955, 3936.
M. M. Popov, Thermometry and Calorimetry [in Russian], Izd. MGU (1954).
S. M. Skuratov, V. P. Kolesov, and A. F. Vorob'ev, Thermochemistry [in Russian], Izd. MGU (1964).
B. N. Oleinik, Exact Calorimetry [in Russian], Izd. Standartov (1964).
R. Prshibil, Complexones in Chemical Analysis [Russian Translation], IL, Moscow (1960).
G. L. Gal'chenko, M. M. Ammer, S. M. Skuratov, Yu. N. Bubnov, and B. M. Mikhailov, Vestnik MGU, No. 2, 3 (1965).
Thermal Constants of Inorganic Substances [in Russian], Moscow-Leningrad (1949).
Experimental Thermochemistry, F. D. Rossini, N.Y.,1 (1956).
L. P. Hammett, Trans. Faraday Soc.,34, No. 1, 156 (1938).
M. M. Kabachnik, Collection: Chemistry and Use of Organophosphorus Compounds [in Russian], Izd. AN SSSR, Moscow (1962), p. 24.
A. V. Nikolaev, I. N. Gribanova, N. I. Yakovleva, V. B. Durasov, I. D. Khol'kina, Z. N. Mironova, E. N. Tsvetkov, and M. I. Kabachnik, Dokl. AN SSSR,165, 578 (1965).
Author information
Authors and Affiliations
Additional information
The article is published on the basis of a resolution of the Conference of Editors-in-Chief of the Journals of the Academy of Sciences of the USSR, of July 12, 1962, as the dissertation work of A. D. Starostin.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1303–1307, August, 1966.
Rights and permissions
About this article
Cite this article
Starostin, A.D., Nikolaev, A.V. & Afanas'ev, Y.A. Standard heats of formation of certain organophosphorus compounds. Russ Chem Bull 15, 1255–1258 (1966). https://doi.org/10.1007/BF01151349
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01151349