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Kinetics and mechanism of the coupled oxidation of propylene and acetaldehyde

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetics and composition of the products of coupled oxidation of propylene and acetaldehyde were studied at the temperature 75° and the pressure 50 atm.

  2. 2.

    Propylene oxide and acetic acid are final products of the reaction; propylene glycol monoacetate is formed parallel with propylene oxide.

  3. 3.

    The basic epoxiding agents in the process of coupled oxidation of propylene and acetaldehyde are acetyl peroxide radicals

    . The reactions of formation of propylene oxide and propylene glycol ester represent a second direction of the reaction of chain propagation, which parallels the reaction of RO2 + with acetaldehyde.

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Literature cited

  1. É. A. Blyumberg, P. I. Valov, D. V. Ivanyukov, Yu. D. Norikov, and N. M. Émanuél', USSR Patent No. 172,296, 1962; Byul. Izobr., No. 13, 1965.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    P. I. Valov, É. A. Blyumberg & N. M. Émanuél'

Authors
  1. P. I. Valov
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  2. É. A. Blyumberg
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  3. N. M. Émanuél'
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1334–1339, August, 1966.

The article is published on the basis of a resolution of the Conference of Editors-in-Chief of the Journals of the Academy of Sciences of the USSR, of July 12, 1962, as the dissertation work of P. I. Valov.

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Valov, P.I., Blyumberg, É.A. & Émanuél', N.M. Kinetics and mechanism of the coupled oxidation of propylene and acetaldehyde. Russ Chem Bull 15, 1283–1287 (1966). https://doi.org/10.1007/BF01151354

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  • DOI: https://doi.org/10.1007/BF01151354

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