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Structures of products of the reactions of halotriorganosilanes with triethyl phosphite and with sodium dialkyl phosphites

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of bromotriethylsilane with triethyl phosphite at high temperatures (155–180°) goes with formation mainly of silyl-substituted tervalent phosphorus derivatives, which readily combine with sulfur and undergo Arbuzov reaction with ethyl bromide.

  2. 2.

    In the reactions of trialkylhalosilanes with sodium diethyl phosphite the products are not quinquevalent phosphorus compounds containing the Si-P bond as was supposed earlier, but the isomeric tervalent phosphorus compounds containing the Si-O-P link.

  3. 3.

    The thione-thiol isomerization of Si-P was effected in presence of ethyl bromide.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    E. F. Bugerenko, E. A. Chernyshev & E. M. Popov

Authors
  1. E. F. Bugerenko
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  2. E. A. Chernyshev
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  3. E. M. Popov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1391–1396.

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Bugerenko, E.F., Chernyshev, E.A. & Popov, E.M. Structures of products of the reactions of halotriorganosilanes with triethyl phosphite and with sodium dialkyl phosphites. Russ Chem Bull 15, 1334–1337 (1966). https://doi.org/10.1007/BF01151366

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  • DOI: https://doi.org/10.1007/BF01151366

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