Conclusions
A new decomposition path to olefin oxide and phosphine has been found for the R3P+C-CO-bipolar ion that forms in the olefin oxide-diphenyl-γ-hydroxyalkylphosphine system. It takes place along with the known degradation paths (formation of unsaturated and carbonyl compounds).
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
G. Wittig, H.-D. Weigmann, and H. Schlosser, Chem. Ber.,94, 676 (1961).
A. J. Speziale and D. E. Bissing, J. Am. Chem. Soc.,85, 1888 (1963).
G. Wittig and W. Boll, Chem. Ber.,95, 2526 (1965).
C. Johnson, C. Schroeck, and J. Shanklin, J. Am. Chem. Soc.,95, 7424 (1973).
A. D. Malievskii and O. I. Gorbunova, Izv. Akad. Nauk SSSR, Ser. Khim., 2307 (1981).
M. C. Henry and G. Wittig, J. Am. Chem. Soc.,82, 563 (1960).
A. D. Malievskii and V. V. Vints, Izv. Akad. Nauk SSSR, Ser. Khim., 2702 (1977).
K. Issleib and H.-R. Roloff, Chem. Ber.,98, 2091 (1965).
N. A. Bondarenko, E. I. Matrosov, E. N. Tsvetkov, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 106 (1980).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimcheskaya, No. 1, pp. 169–173, January, 1985.
Rights and permissions
About this article
Cite this article
Malievskii, A.D., Gorbunova, O.I., Bondarenko, N.A. et al. New path for the decomposition of bipolar adducts formed by the reaction of olefin oxides with diphenyl-β-hydroxyalkylphosphines. Russ Chem Bull 34, 158–161 (1985). https://doi.org/10.1007/BF01157345
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01157345