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Preparation and X-ray structure of [H3O+·18-crown-6]-[(H5O +2 )(Cl−)2], a compound containing both H3O+ and H5O +2 crystallized from aromatic solution

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Abstract

The title compound was synthesized by the reaction of [H3O+·18-crown-6][Cl-H-Cl−]·3.8 C6H5Me with two equivalents of H2O. Colorless crystals, which slowly deposited from the corresponding liquid clathrate, belong to the monoclinic space group P21/n witha=10.648(6),b=9.571(2),c=20.801(6) Å,β=98.67(5)°, andD c=1.24 g cm−3 forZ=4. Refinement based on 1609 observed reflections led to a finalR value of 0.072. In the crystal structure the [H3O+·18-crown-6]+ cations are packed in layers separated by puckered sheets of [(H5O +2 )(Cl−)2]−.

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Authors and Affiliations

  1. Department of Chemistry, University of Alabama, 35487, Tuscaloosa, Alabama

    Jerry L. Atwood, Simon G. Bott, Kerry D. Robinson, Elizabeth J. Bishop & Michael T. May

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  1. Jerry L. Atwood
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  2. Simon G. Bott
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  3. Kerry D. Robinson
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  4. Elizabeth J. Bishop
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  5. Michael T. May
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Atwood, J.L., Bott, S.G., Robinson, K.D. et al. Preparation and X-ray structure of [H3O+·18-crown-6]-[(H5O +2 )(Cl−)2], a compound containing both H3O+ and H5O +2 crystallized from aromatic solution. Journal of Crystallographic and Spectroscopic Research 21, 459–462 (1991). https://doi.org/10.1007/BF01160659

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  • DOI: https://doi.org/10.1007/BF01160659

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