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Crystal structure of [bis 1,2-(diphenylphosphino)ethane]-bis(pyridine-2-thiolato)ruthenium(II)

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Abstract

The Ru atom in the title compound, [Ru(dppe)(2-pyS)2] exists in a distorted octahedral geometry defined by a dppe ligand and two 2-pyS anions which function as bidentate ligands via their N- and S-atoms. Important interatomic parameters are Ru-P2.240(3), 2.256(3); Ru-N 2.131(8), 2.136(8); Ru-S 2.413(3), 2.428(3) Å; P-Ru-P 84.1(1), S-Ru-S 155.0(1) and N-Ru-N 87.5(3)°. Crystals are monoclinic, space groupP21/c, with unit cell dimensionsa=10.342(1),b=31.145(6),c=11.107(2) Å,β=113.80(1)° andZ=4. The structure was refined to finalR=0.064 for 3057 reflections withI≥2.5σ(I).

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Authors and Affiliations

  1. Jordan Laboratories, Department of Physical and Inorganic Chemistry, University of Adelaide, 5001, Adelaide, South Australia, Australia

    Edward R. T. Tiekink

  2. Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India

    Tarlok S. Lobana & Randhir Singh

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  1. Edward R. T. Tiekink
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  2. Tarlok S. Lobana
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  3. Randhir Singh
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Tiekink, E.R.T., Lobana, T.S. & Singh, R. Crystal structure of [bis 1,2-(diphenylphosphino)ethane]-bis(pyridine-2-thiolato)ruthenium(II). Journal of Crystallographic and Spectroscopic Research 21, 205–208 (1991). https://doi.org/10.1007/BF01161066

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  • DOI: https://doi.org/10.1007/BF01161066

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