Abstract
The structure of tetraacetylethane has been determined by neutron diffraction. The compound exists in the dienolic form, the enolic hydrogen being intramolecularly bonded to a neighbouring oxygen in a clearly asymmetric mode. The acetylacetonate residues are essentially planar.
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Coppens, P. & Hamilton, W. C. (1970)Acta Crystallogr. A26, 71.
Engebretson, G. R. & Rundle, R. E. (1964)J. Amer. Chem. Soc. 86, 574.
Moore, F. H. & Power, L. F. (1971)Inorg. Nucl. Chem. Letters 7, 873.
O'Connor, B. H. (1969) UWAC-23, The University of Western Australia Computer Centre.
Power, L. F. & Jones, R. D. G. (1971a)Acta Crystallogr. B27, 181.
Power, L. F. & Jones, R. D. G. (1971b)Inorg. Nucl. Chem. Letters 7, 35.
Power, L. F. & Jones, R. D. G. (1971c)Inorg. Nucl. Chem. Letters 7, 887.
Power, L. F., Turner, K. E. & Moore, F. H. (1912)Inorg. Nucl Chem. Letters 8, 313.
Power, L. F., Turner, K. E. & Moore, F. H. (1974)Tetrahedron Letters 875.
Schaefer, J. P. & Wheatley, P. J. (1966)J. Chem. Soc. (A), 528.
Semmingsen, D. (1972)Acta Chem. Scand. 26, 143.
Williams, D. E. (1966)Acta Crystallogr. 21, 340.
Williams, D. E., Dumke, W. L. & Rundle, R. E. (1962)Acta Crystallogr. 15, 627.
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Power, L.F., Turner, K.E. & Moore, F.H. Refinement of the crystal and molecular structure of tetraacetylethane by neutron diffraction. Journal of Crystal and Molecular Structure 5, 59–66 (1975). https://doi.org/10.1007/BF01202552
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DOI: https://doi.org/10.1007/BF01202552