Skip to main content
SpringerLink
Log in

Crystal growth of chemical Co-P and electrodeposited Co on Ni and Cu single crystals

Part 1 (0 0 1) faces

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The crystal growth of Co-P alloys chemically reduced with hypophosphites from aqueous solutions on the (0 0 1) faces of Ni and Cu single crystals has been studied in a wide range of thicknesses: 10 Å to 12μm. Smooth deposits ofβ-Co and martensitically transformedα-Co are first obtained. Upon increasing the thickness, outgrowth is observed and the mechanism of formation is attributed to an anomalous (1 0. 1) twinning mode. At high thickness, outgrowing basal planes become perpendicular to the base, transform towards the growth mode imposed by the bath and form regions of equi-oriented planes. Electrodeposition of Co films at medium thickness yields similar results.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. E. Collins andO. S. Heavens,Proc. Phys. Soc. B70 (1957) 265.

    Google Scholar 

  2. T. Honma andC. M. Wayman,J. Appl. Phys. 36 (1965) 2791.

    Google Scholar 

  3. N. Takahashi andH. Martina,Compt. Rend. Acad. Sci. Paris.263 (1966) 21.

    Google Scholar 

  4. L. V. Kirenski, V. G. Pynko, N. J. Sivkov, G. P. Pynko, R. V. Sukhanova andM. A. Ovsyannikov,Phys. Stat. Sol. 17 (1966) 243.

    Google Scholar 

  5. H. Gärtner andE. Schelzke,Phys. Stat. Sol. 17 (1966) K 241.

    Google Scholar 

  6. K. Otsuka andC. M. Wayman,ibid 22 (1970) 875.

    Google Scholar 

  7. T. Kato andS. Ogawa,Jap. J. Appl. Phys. 9 (1970) 875.

    Google Scholar 

  8. J. J. Patrician andC. M. Wayman,Phys. Stat. Sol. A 6 (1971) 111, 449, 461.

    Google Scholar 

  9. S. S. Palatnik, B. A. Savitski, M. Yu. Usenko andA. J. Fedorenko,Fiz. Met. Metalloved. 34 (1972) 649.

    Google Scholar 

  10. B. K. Middleton,Phys. Stat. Sol. A 12 (1972) 67.

    Google Scholar 

  11. H. Sato, R. S. Toth andR. W. Astrue,J. Appl. Phys. 34 (1963) 1062.

    Google Scholar 

  12. L. Wray andM. Prutton,Thin Solid Films 15 (1973) 173.

    Google Scholar 

  13. W. A. Jesser andJ. W. Matthews,Acta Met. 16 (1968) 1307.

    Google Scholar 

  14. W. A. Jesser andJ. W. Matthews,Phil. Mag. 17 (1968) 461.

    Google Scholar 

  15. J. W. Matthews,ibid 17 (1968) 1149.

    Google Scholar 

  16. E. Grünbaum andG. Kremer,J. Appl. Phys. 39 (1968) 347.

    Google Scholar 

  17. R. Buder andO. Massenet,Compt. Rend. Acad. Sci. Paris B 269 (1969) 744.

    Google Scholar 

  18. E. Grünbaum, G. Kremer andC. Reymond,J. Vac. Sci. Technol. 6 (1969) 475.

    Google Scholar 

  19. J. W. Matthews,Thin Solid Films 5 (1970) 369.

    Google Scholar 

  20. A. J. Fedorenko andR. Vincent,Phil. Mag. 24 (1971) 55.

    Google Scholar 

  21. W. Cochrane,Proc. Phys. Soc. 48 (1936) 723.

    Google Scholar 

  22. G. I. Finch, H. Wilman andL. Yang,Discuss. Faraday Soc. 1 (1947) 144.

    Google Scholar 

  23. R. C. Newman,Proc. Phys. Soc. B 69 (1956) 432.

    Google Scholar 

  24. S. Fukuda,J. Appl. Phys. Japan 27 (1958) 236.

    Google Scholar 

  25. J. Goddard andJ. G. Wright,Brit. J. Appl. Phys. 15 (1964) 807,J. G. Wright,Thin Solid Films 22 (1974) 197.

    Google Scholar 

  26. J. E. Fisher,Thin Solid Films 17 (1973) S 31.

    Google Scholar 

  27. R. D. Fisher andW. H. Chilton,J. Electrochem. Soc. 109 (1962) 485;Plating 55 (1968) 263.

    Google Scholar 

  28. R. D. Fisher andD. E. Koopmann,J. Electrochem. Soc. 112 (1964) 263.

    Google Scholar 

  29. L. D. Ransom andV. Zentner,ibid 111 (1964) 1423.

    Google Scholar 

  30. L. Cadorna, P. Cavallotti andG. Salvago,Electrochim. Metall 1 (1966) 177.

    Google Scholar 

  31. J. S. Judge, J. R. Morrison, D. E. Speliotis andG. Bate,J. Electrochem. Soc. 112 (1965) 681;113 (1966) 547.

    Google Scholar 

  32. M. G. Miksic, R. Travieso, A. Arcus andR. H. Wright,ibid 113 (1966) 360.

    Google Scholar 

  33. R. D. Fisher andS. D. Taylor,J. Appl. Phys 37 (1966) 2752.

    Google Scholar 

  34. A. S. Frieze, R. Sard andR. Weil,J. Electrochem. Soc. 115 (1968) 586.

    Google Scholar 

  35. V. P. Moisseiev, G. A. Sadakov andK. M. Gorbunova,Russ. J. Phys. Chem. 42 (1968) 1463.

    Google Scholar 

  36. G. A. Jones andB. K. Middleton,J. Mater. Sci. 3 (1968) 519.

    Google Scholar 

  37. V. Morton andR. D. Fisher,J. Electrochem. Soc. 116 (1969) 188.

    Google Scholar 

  38. P. Cavallotti andG. Salvago,ibid 116 (1969) 819.

    Google Scholar 

  39. M. Aspland, G. A. Jones andB. K. Middleton,J.E.E.E. Trans. 5 (1969) 314.

    Google Scholar 

  40. S. L. Chow, N. E. Hedgecock, M. Schlesinger andJ. Rezek,J. Electrochem. Soc. 119 (1972) 1013, 1614.

    Google Scholar 

  41. J. R. De Pew,J. Electrochem. Soc. 120 (1973) 120.

    Google Scholar 

  42. G. A. Jones andM. Aspland,Phys. Stat. Sol. A 11 (1972) 637.

    Google Scholar 

  43. R. Piontelli,Electrochim. Metall. 1 (1966) 5.

    Google Scholar 

  44. J. Kuta andE. Yeager, in “Techniques of Electrochemistry”, Vol. 1, edited by E. Yeager and A. J. Salkind Interscience, New York, 1972).

    Google Scholar 

  45. L. Cadorna andP. Cavallotti,Electrochim. Metall. 1 (1966) 364.

    Google Scholar 

  46. W. B. Pearson, “A Handbook of Lattice Spacings and Structures of Metals and Alloys”, Vol. II (Pergamon Press, Oxford, 1967) p.779.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Istituto di Chimica Fisica, Elettrochimica e Metallurgia, CNPM, Politecnico, Milano, Italy

    P. Cavallotti & S. Noer

Authors
  1. P. Cavallotti
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Noer
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cavallotti, P., Noer, S. Crystal growth of chemical Co-P and electrodeposited Co on Ni and Cu single crystals. J Mater Sci 11, 645–655 (1976). https://doi.org/10.1007/BF01209450

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01209450

Keywords

Search

Navigation