Abstract
Illinois coal was ground and wet-sieved to prepare three powder stocks whose particle-size distributions were characterized. Three suspending fluids were used (glycerin, bromonaphthalene, Aroclor), with viscositiesη s that differed by a factor of 100 and with very different chemistries, but whose densities matched that of the coal. Suspensions were prepared under vacuum, with coal volume fractionsφ that ranged up to 0.46. Viscosities were measured in a cone-and-plate over a shear rate\((\dot \gamma )\) range 10−3−102 s−1. Reduced viscosityη r = η/ηs is correlated in the high-shear limit (η ∞) withφ/φ M∞, whereφ M∞ is the maximum packing fraction for the high-shear microstructure, to reveal the roles of size distribution and suspending fluid character. A new model that invokes the stress-dependence ofφ M is found to correlateη r well under non-Newtonian conditions with simultaneous prediction of yield stress at sufficiently highφ; a critical result is that stress and not\(\dot \gamma \) governs the microstructure and rheology. Numerous experimental anomalies provide insight into suspension behavior.
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Thurgood JR, Hanks RW, Youngblood EL (1982) AIChE J 28:111
Chemical & Engineering News, Sept. 25, 1978, p 43
Wildemuth CR, Williams MC (1984) Rheol Acta 23:627
Wildemuth CR (1980) M.S. thesis, University of California. Berkeley
Krieger IM, Dougherty TJ (1959) unpublished manuscript. Also, Dougherty TJ, Ph.D. Thesis, Case Institute of Technology, Cleveland, Ohio, 1959. See remarks in: Krieger IM (1972) Adv Colloid Interface Sci 3:111
Castillo C, Williams MC (1979) Chem Eng Commun 3:529
Landel RF, Moser BG, Bauman AJ (1965) in: Lee EH (ed), Proc. 4th Intern. Congr. Rheol., John Wiley & Sons, New York, Part 2, p 663
Weast RC, ed (1971) Handbook of Chemistry and Physics, 52nd edition, Chemical Rubber Company, Cleveland, OH
Chong JS, Christiansen EB, Baer AD (1971) J Appl Polym Sci 15:2007
Farris RJ (1968) Trans Soc Rheol 12:281
Adams-Viola M, Botsaris GD, Glazman Y (1982) AIChE J 28:392
Lewis TB, Nielsen LE (1968) Trans Soc Rheol 12:421
Moreland C (1963) Canadian J Chem Eng 41:24
Beazley KM (1972) J Colloid Sci 41:105
Monro JM, Lewellyn MM, Crackel PR, Bauer LG (1979) AIChE J 25:355
Maschmeyer RO, Hill CT (1977) Trans Soc Rheol 21:195
Kao SV, Nielsen LE, Hill CT (1975) J Colloid Interface Sci 53:358
Thomas DG (1961) AIChE J 71:431
Eilers H (1941) Kolloid-Z 97:313
Maron SH, Levy-Pascal AE (1955) J Colloid Sci 53:494
Maron SH, Belner RJ (1955) ibid., p 523
Maron SH, Fok SM (1955) ibid., p 482
Krieger IM, Dougherty TJ (1959) Trans Soc Rheol 3:137
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Wildemuth, C.R., Williams, M.C. A new interpretation of viscosity and yield stress in dense slurries: Coal and other irregular particles. Rheol Acta 24, 75–91 (1985). https://doi.org/10.1007/BF01329266
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DOI: https://doi.org/10.1007/BF01329266