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On the extensional viscosity of mobile polymer solutions

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Abstract

We describe experimental results on the extensional viscosity of mobile polymer solutions obtained from two instruments, the first being a commercial Spin Line Rheometer and the second a custom-built lubricated-die Converging Flow Rheometer. The interpretation of data in terms of Trouton ratios is facilitated by a simple analysis for the Generalized Newtonian Fluid model.

Agreement between data from the two rheometers is satisfactory and we show that polymer solutions can be either tension stiffening or tension thinning. However, the Trouton ratios in both cases are greater than the Newtonian values and we anticipate that this will always be the case for polymer solutions.

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Jones, D.M., Walters, K. & Williams, P.R. On the extensional viscosity of mobile polymer solutions. Rheol Acta 26, 20–30 (1987). https://doi.org/10.1007/BF01332680

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  • DOI: https://doi.org/10.1007/BF01332680

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