Skip to main content
Log in

Influence of disperse phase concentration upon the viscoelastic behaviour of emulsions

  • Original Contributions
  • Published:
Rheologica Acta Aims and scope Submit manuscript

Abstract

Rheology of soya oil-water emulsions in the linear region has been studied. The viscoelastic response consisted of three contributions. There was a purely elastic component, a purely viscous component and a contribution due to the retarded compliance. Emulsions became more viscous and elastic with increasing soya oil concentration. Sharp changes in rheology were observed as the concentration approached the random close packed limit. There was also a marked increase in zero-shear viscosity. Breakdown of coagulation structure was observed as the shear stress was increased into the non-linear region. The rheological behaviour of the emulsions in the linear region could be adequately described by the generalized Kelvin-Voigt model.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Leaderman H (1958) In: Eirich FR (ed), Rheology, theory and applications, vol 2. Academic Press, New York

    Google Scholar 

  2. Bland DR (1960) The theory of linear viscoelasticity. Pergamon Press, New York

    Google Scholar 

  3. Purkaystha S, Peleg M, Normand MD (1984) Rheol Acta 23:556

    Google Scholar 

  4. Sherman P (1967) J Colloid Interface Sci 24:107

    Google Scholar 

  5. Sherman P (1970) In: Onogy S (ed) Proc V. Intern Congr Rheol vol 2, p 327. University of Tokyo Press

  6. Lyklema J, van den Tempel M, van Vliet T (1978) Rheol Acta 17:525

    Google Scholar 

  7. Zosel A (1982) Rheol Acta 21:72

    Google Scholar 

  8. Maron SH, Sisko AH (1957) J Colloid Sci 12:99

    Google Scholar 

  9. Payne AR (1964) J Colloid Sci 19:744

    Google Scholar 

  10. Rehbinder P (1965) Pure Appl Chem 10:337

    Google Scholar 

  11. Rehbinder P (1970) In: Onogy S (ed) Proc V. Intern Congr Rheol, vol 2, p 375. University of Tokyo Press

  12. Hennock M, Rahalkar RR, Richmond P (1984) J Food Sci 49:1271

    Google Scholar 

  13. Whorlow RW (1980) Rheological Techniques. J. Wiley, London

    Google Scholar 

  14. Scott GD (1960) Nature 108:908

    Google Scholar 

  15. Verwey EJW, Overbeek ITG (1948) Theory of the stability of lyphobic colloids. Amsterdam

  16. Derjaguin BV, London LD (1941) Acta Phys Chim USSR 14:633

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gladwell, N., Rahalkar, R.R. & Richmond, P. Influence of disperse phase concentration upon the viscoelastic behaviour of emulsions. Rheol Acta 25, 55–61 (1986). https://doi.org/10.1007/BF01369980

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01369980

Key words

Navigation