Summary
Bis-(5-nitro-1,10-phenanthroline)platinum(II) dichloride and diperchlorate have been prepared. The reaction between the parent cation and hydroxide ion has been studied using 1 FI n.m.r. spectroscopy and found to involve attack at the ligand. The bis-(2,2′-bipyridyl)platinum(II) ion has been shown to be highly reactive towards methoxide ion. The dissociation of a 2,2′-bipyridyl ligand is preceded by attack at the ligand.
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References
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Part XI: R. D. Gillard, t.. A. P. Kane-Maguire and P. A. Williams,Transition Met. Chem., 2, 47 (1977).
On leave from the University of Baghdad, Iraq.
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Al-Obaidi, K.H., Gillard, R.D., Kane-Maguire, L.A.P. et al. Equilibria in complexes of N-heterocyclic molecules, part XII. The reaction of hydroxide and alkoxide Ions with platinum(II) complexes of 5-nitro-1,10-phenanthroline and 2,2′-bipyridyl. Transition Met Chem 2, 64–66 (1977). https://doi.org/10.1007/BF01402685
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DOI: https://doi.org/10.1007/BF01402685