Summary
A number of alcoholate complexes of chromium chloride with the general formula, CrCl3 · xROII (R = Me, Et, i-Pr, n-Bu and n-Ilexyl; x = 3 and 4) have been synthesized by the reactions of CrCl3 · 3 TIIF with an excess of the appropriate alcohols under reflux. Physicochemical studies such as i.r., visible reflectance, electron spin resonance spectra and thermogravimetric measurements, in addition to elemental analyses, throw light on the structure of these complexes.
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References
R. C. Mehrotra,Inorg. Chim. Acta, 1, 99 (1967).
J. H. Harwood,Industrial Applications of Organometallic Compounds, Chapman and Hall, London, 1963.
D. C. Bradley,Advan. Inorg. Chem. Radiochem. 15, 259 (1973).
D. C. Bradley,Progr. Inorg. Chem., 2, 303 (1960).
A. G. Kruger and G. Winter,Aust. J. Chem., 23, 1 (1970.
L. Dubicki, G. A. Kakos and G. Winter,Aust. J. Chem., 21, 1461 (1968).
D. A. Brown, D. Cunningham and W. K. Glass,J. Chem. Soc. A, 1 563 (1968).
E. C. Alyea, J. S. Basi, D. C. Bradley and M. H. Chisholm,J. Chem. Soc. A, 772 (1971).
L. J. Bellamy,The Infrared Spectra of Complex Molecules, Chapman and Hall, London, 1975.
L. Pederson and S. Kallesoe,Inorg. Chem., 14, 85 (1975).
B. A. Goodman and J. B. Raynor,Advan. Inorg. Chem. Radiochem., 13, 136 (1970).
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Mehrotra, R.C., Bharara, P.C. & Mahendra, K.N. Alcoholate complexes of chromium(III) chloride. Transition Met Chem 2, 161–163 (1977). https://doi.org/10.1007/BF01402712
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DOI: https://doi.org/10.1007/BF01402712