Abstract
A novel reaction of the sodium salt of 2-nitroethanol in aqueous ammonia resulted in the sodium salt of 2-oxo-3-hydroxypropionic acid oxime (1) has been found. Bromination of1 affords 2-bromo-2-nitropropane-1,3-diol (2) with a previously unknown molecular conformation. The formation mechanisms of compounds1 and2 were suggested. X-ray analysis of products1,2 and that of the model compound, 2,2-dinitropropane-1,3-diol, was performed.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1217–1221, May, 1996.
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Fedorov, B.S., Gotovina, N.L., Arakcheeva, V.V. et al. New reaction of the sodium salt of 2-nitroethanol. X-ray analysis of the sodium salt of 2-oxo-3-hydroxypropionic acid oxime, 2-bromo-2-nitropropane-1,3-diol, and the model 2,2-dinitropropane-1,3-diol. Russ Chem Bull 45, 1157–1161 (1996). https://doi.org/10.1007/BF01431611
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DOI: https://doi.org/10.1007/BF01431611