Abstract
Dynamics of changes in microstresses during thermal decomposition of Cu(HCOO)2 crystals and their effect on the thermal decomposition kinetics were studied by IR spectroscopy at 105 to 120 °C. The formation of solid intermediate HCOOCu was observed, and the dynamics of its accumulation was followed. Kinetic regularities of transformation of HCOO groups were compared with those for gas evolution.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. S. Rozenberg and E. I. Aleksandrova,Izv. Akad. Nauk, Ser. Khim., 1996,45, 71 [Russ. Chem. Bull., 1996,45, 64 (Engl. Transl.)].
N. V. Chukanov, L. V. Berlyand, B. L. Korsunskii, and V. A. Dubovitskii,Zh. Fiz. Khim., 1990,64, 1824 [Russ. J. Phys. Chem., 1990,64 (Engl. Transl.)].
E. V. Deyun, G. B. Manelis, E. B. Polianchik, and L. P. Smirnov,Usp. Khim., 1980,49, 1574 [Russ. Chem. Rev., 1980,49 (Engl. Transl.)].
B. E. Krisyuk, A. A. Popov, and G. E. Zaikov,Vysokomol. Soedin., Ser. A, 1980,22, 329 [Polym. Sci. USSR, 1980,22 (Engl. Transl.)].
V. A. Benderskii, V. M. Beskrovnyi, E. Ya. Misochko, and P. G. Filippov,Dokl. Akad. Nauk SSSR, 1983,273, 364 [Dokl. Chem., 1983,273 (Engl. Transl.)].
A. A. Sidel'nikov, A. P. Chupakhin, and V. V. Boldyrev,Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk [Bull. Sib. Branch Acad. Sci. USSR, Div. Chem. Sci.], 1985,17, 49 (in Russian).
N. N. Sirota, inKinetika i mekhanizm kristallizatsii [Kinetics and Mechanism of Crystallization], Nauka i Tekhnika, Minsk, 1973, 41 (in Russian).
S. N. Zhurkov,J. Fract. Mater., 1965,4, 311.
D. M. Adams and T.-K. Tan,J. Chem. Soc., Faraday Trans. 2, 1981,77, 1711.
S. N. Zhurkov, V. I. Vittegren', V. E. Korsunkov, and I. I. Novak,Fiz.. Tverd. Tela [Solid State Phys.], 1969,11, 290 (in Russian).
V. V. Baptizmanskii and I. I. Novak,Fiz. Tverd. Tela [Solid State Phys.], 1975, 17, 1989 (in Russian); K. N. Kuksenko, I. I. Novak, and V. P. Pukh,Zh. Prikl. Spektrosk. [Zh. Appl. Spectrosc.], 1975,22, 1048 (in Russian).
J. McBride and J. Michael,Ace. Chem. Res., 1983,16, 304.
L. V. Berlyand, N. V. Cliukanov, and V. A. Dubovitsky,Chem. Phys. Lett., 1991,181, 450.
N. V. Chukanov, D. Sci. (Chem.) Thesis, Chernogolovka, 1991 (in Russian).
K. Nakamoto,Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1986.
S. Schuffenecker, Y. Trambouze, and M. Prette,Ann. Chim. (Paris), 1962,7, 133.
A. K. Galway, D. M. Jamirson, and M. S. Brown,J. Phys. Chem., 1974,78, 2664.
V. V. Aleksandrov, V. V. Boldyrev, V. A. Bocharnikov, and V. G. Morozov, inTezisy soveshch. po kinetike i mekhanizmu khim. reaktsii v tverdom tele [Proc. Meeting on Kinetics and Mechanism of Solid-Phase Chemical Reactions], Part 1, Novosibirsk, 1977, 133 (in Russian).
R. A. Lidin, L. L. Andreev, and V. A. Molochko,Sprav. po neorganicheskoi khimii. Konstanty neorganicheskikh veschestv [Manual on Inorganic Chemistry. Constants of Inorganic Substances], Khimiya, Moscow, 1987, 210 (in Russian).
A. W. Baker,J. Phys. Chem., 1957,61, 450.
Author information
Authors and Affiliations
Additional information
For Communication 1, see Ref. 1.
Translated from Izvestiya va Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 350–354, February, 1996.
Rights and permissions
About this article
Cite this article
Rozenberg, A.S., Chukanov, N.Y. Thermal decomposition of transition metal carboxylates. Russ Chem Bull 45, 335–339 (1996). https://doi.org/10.1007/BF01433967
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01433967