Abstract
Thermal decomposition of anhydrous Cu(HCOO)2 (1) affords H2, CO, CO2, H2O, HCuOOH, CuHCOO, Cu, and the polymeric product, which contains -CH2O,-C(O)OH-, and -RCH-0- groups. Dccomposition of1 proceeds in stages with formation of copper(I) formate as an intermediate. Possible pathways of decomposition ofI, including isomeric forms of the HCO2 radical as intermediates, were analyzed.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1406–1412, June, 1996.
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Rozenberg, A.S., Stepanov, V.R. Thermal decomposition of transition metal carboxylates. Russ Chem Bull 45, 1336–1343 (1996). https://doi.org/10.1007/BF01434208
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DOI: https://doi.org/10.1007/BF01434208