Abstract
Reactions of a tetranuclear palladium cluster [Pd(CO)(OAc)[4 with C1-C3 alcohols have been found to proceed simultaneously via several routes to form CO, and dialkyl carbonates, the products of oxidation of coordinated CO ligands, along with carbonyl compounds which form due to oxidation of the corresponding alcohols. Alkoxy, alkoxycarbonyl, and acyl palladium derivatives are shown to be the intermediates of the reactions studied.
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References
Yu. B. Yan and B. K. Nefedov,Sintezy no osnove oksidov ugleroda [Synthesis Based on Carbon Oxides], Khimiya, Moscow, 1987, 263 (in Russian).
Catalysis in C1 Chemistry, Eds. W. fnKeim and D. Reidel, Dordrecht, 1983.
G. E. Morris, D. Oakley, D. A. Pippard, and D. J. H. Smith,J. Chem. Soc., Chem. Commun., 1987, 410.
G. E. Morris, D. Oakley, and D. A. Pippard,J. Chem. Soc., Chem. Commun., 1987, 411 .
D. M. Fenton and R. J. Steinwand,J. Org. Chem., 1972,37, 2034.
D. Delledonne, F. Rivetti, and U. Romano,J. Organometal. Chem., 1995488, 15.
O. N. Temkin, O. L. Kaliya, L. N. Zhir-Lebed, V. A. Golodov, L. G. Bruk, and N. G. Mekhryakova,Akad. Nouk Kaz. SSR, Trudy IOKE. Gomogennoe okislenie [Proceedings of IOKE. Gomogeneous Oxidation], Nauka, AlmaAta, 1978, 17, 3 (in Russian).
D. M. Fenton and R. J. Steinwand,J. Org. Chem., 1974,39, 701.
F. Rivetti and U. Romano,J. Organometal. Chem., 1978,154, 323.
L. N. Zhir-Lebed, L. G. Kuz'mina, Yu. T. Struchkov, and O. N. Temkin,Koord. Khim., 1978,4, 1046 [Sov. J. Coord. Chem., 1978,4 (Engl. Transl.)].
O. N. Temkin and L. G. Bruk,Usp. Khim., 1983,52, 206 [Russ. Chem. Rev., 1983,52 (Engl. Transl.)].
T. A. Stromnova, N. Yu. Tikhonova, L. K. Shubochkin, and I. I. Moiseev,Koord. Khim., 1993,19, 450 [Russ. J. Coord. Chem., 1993,19 (Engl. Transl.)].
A. Weissberger, E. S. Proskauer, J. A. Riddick, and E. E. Toops, Jr,Organic Solvents. Physical Properties and Methods of Purification, Interscience Publ., New York, 1955.
T. A. Stromnova, M. N. Vargaftik, and I. I. Moiseev,J. Organometal. Chem., 1983,252, 113
Jap. Pat. 7984514;Chem. Abstr., 1979,91, 157294a.
I. S. Kolomnikov and M. Kh. Grigoryan,Usp. Khim., 1978,47, 603 [Russ. Chem. Rev., 1978,47 (Engl. Transl.)].
I. I. Moiseev, Ya. K. Syrkin, and A. V. Nikiforova,Zh. Obshch. Khim., 1963,33, 3239 [J. Gen. Chem. USSR, 1963,33 (Engl. Transl.)].
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2456–2459, October, 1996.
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Chernysheva, T.V., Stromnova, T.A., Vargaftik, M.N. et al. Reactions of palladium(I) carbonylacetate cluster with alcohols. Russ Chem Bull 45, 2327–2330 (1996). https://doi.org/10.1007/BF01435376
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DOI: https://doi.org/10.1007/BF01435376