Abstract
TheK absorption edge of Si in matrix isolated SiO molecular clusters was studied for various dilutionsR(Ar/SiO). The spectra from the clusters at different dilutions show a dramatic evolution in their relative intensity. Two types of spectral features from Si atoms present in the clusters could be detected in the spectra. The first is due to the Si atoms which are tetrahedrally coordinated to Si and O atoms responsible for the presence of different Si oxidation states. The Si+, Si3+ and Si4+ oxidation states in SiO clusters and in bulk were readily identified. The Si2+ oxidation state whose abundance in SiO clusters is predicted by structural considerations is not clearly observed. The second type of feature, whose intensity decreases with the dilution R, can be attributed to the presence of Si atoms possessing unsaturated bonds. In order to explain this the clustering of 4–6 SiO molecules is simulated to yield different tetrahedral bonding microstructures in which the well coordinated as well as under coordinated Si atoms are present. The behaviour of the spectral features resulting from these microstructures is discussed.
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Physics and chemistry of small clusters. Jena, P., Rao, B.K., Khanna, S.N. (eds.), NATO ASI Series, vol 158. New York: Plenum Press 1987
Small particles and inorganic clusters — Chapon, C., Gillet, M.F., Henry, C.R. (eds.): Z. Phys. D — Atoms, Molecules and Clusters12, (1989)
Chemistry and physics of matrix isolated species Andrews, L., Moskovits, M. (eds.). Amsterdam: North Holland 1989
“Les agrégats inorganiques élémentaires” — Joyes, P. (ed.) Les editions de physique, Les Ulis, France 1990
Montano, P.A., Zhao, J., Ramanathan, M., Shenoy, G.K., Schultze, W.: Z. Phys. D — Atoms, Molecules and Clusters12, 103 (1989)
Lübcke, M., Sonntag, B., Niemann, W., Rabe, P.: Phys. Rev. B34, 5184 (1986)
Niemann, W., Malzfeldt, W., Rabe, P., Haensel, R., Lübcke, M.: Phys. Rev. B35, 1099 (1987)
Blancard, C., Esteva, J.M., Karnatak, R.C., Connerade, J.P., Kuetgens, U., Hormes, J.: J. Phys. B22, L575 (1989)
Blancard, C., Esteva, J.M., Karnatak, R.C., Connerade, J.P., Kuetgens, U., Hormes, J.: Conf. Proc, vol. 25, 2nd European Conf. on Progress in X-ray Synchrotron Radiation Research. Balerna, A., Bernieri, E., Mobilio, S (eds.), p. 113 SIF, Bologna, Italy, 1990
Blancard, C., Esteva, J.M., Karnatak, R.C., Sarpal, B.K., Connerade, J.P., Kuetgens, U., Hormes, J.: Conf. Proc, vol. 25, 2nd European Conf. on Progress in X-ray Synchrotron Radiation Research. Balerna, A., Bernieri, E., Mobilio, S. (eds.), p. 117. SIF, Bologna, Italy, 1990
Connerade, J.P., Karnatak, R.C.: Comment At. Mol. Phys.24, 1 (1990)
Esteva, J.M., Karnatak, R.C., Connerade, J.P.: J. Electron Spectrosc. Relat. Phenom.31, 1 (1983)
Tulier, M.H., Laporte, D., Esteva, J.M.: Phys. Rev. A26, 372 (1982)
Bodeur, S., Esteva, J.M.: Chem. Phys.100, 415 (1985)
Bouisset, E., Esteva, J.M., Karnatak, R.C., Connerade, J.P., Flank, A.M., Lagarde, P.: J. Phys. B.24, 1609 (1991)
Thole, B.T., Laan, G. van der, Fuggle, J.C., Sawatzky, G.A., Karnatak, R.C., Esteva, J.M.: Phys. Rev. B32, 5107 (1985)
Radzig, A.A., Smirnov, B.M.: Reference data on atoms, molecules and ions, p. 351. Berlin, Heidelberg, New York: Springer 1985
Zmbov, K.F.; Ames, L.L., Margrave, J.L.: High Temp. Sci.5, 235 (1973)
Baig, M.A., Connerade, J.P.: J. Phys. B12, 2309 (1979)
Baig, M.A., Connerade, J.P.: J. Mol. Spectrosc.83, 31 (1980)
Brewer, L., Green, F.T.: J. Chem. Phys. Solids2, 286 (1957)
Temkin, R.J.: J. Non-Cryst. Solids17, 215 (1975)
Ching, W.Y.: Phys. Rev. B26, 6610 (1982)
Dupree, R., Holland, D., Williams, D.S.: Philos. Mag. B50, L13 (1984)
Phillip, H.R.: J. Non-Cryst. Solids8–10, 627 (1972)
Hübner, K.: Phys. Status Solidi40, 133 (1977);42 501 (1977);61, 665 (1980)
Bell, F.G., Ley, L.: Phys. Rev. B37, 8383 (1988)
The physics of SiO2, and its interfaces, Pantalide, S.T. (ed.). New York: Pergamon Press
Himpsel, F.J., McFeely, F.R., Taleb-Ibrahimi, A., Yarmoff, J.A., Hollinger, G.: Phys. Rev. B38, 6084 (1988)
D'Evelyn, M.P., Nelson, M.M., Engel, T.: Surf. Sci.186, 75 (1987)
Marin, P.C.: Nucl. Instrum. Methods A266, 18 (1988)
Lemonnier, M., Collet, O., Depautex, C., Esteva, J.M., Raoux, D.: Nucl. Instrum. Methods153, 109 (1978)
Henke, B.L., Lee, P., Tanaka, P.J., Shimabukuro, R.L., Fujikawa, B.K.: At. Data Nucl. Data Tables27, 1 (1982)
Gullikson, E.: Phys. Rev. B37, 7904 (1988)
Belot, V., Corriu, R.J.P., Leclercq, D., Lefevre, P., Mutin, H., Vioux, A., Flank, A.M.: J. Non-Cryst. Solids127, 207 (1991)
Hollinger, G., Jugnet, Y., Tran Minh Duc: Solid State Commun22, 277 (1977)
Martinez, E., Yndurain, F.: Phys. Rev. B24, 5718 (1981)
Lagarde, P., Flank, A.M., Esteva, J.M., Karnatak, R.C. (unpublished)
Synder, L.C., Raghavachari, K.: J. Chem. Phys.80, 5076 (1984)
Foulis, D., Flank, A.M.: In: X-ray absorption fine structure, p. 41, Samar Hashnain S. (ed.). London: Ellis Horwood 1991
Pauthe, M., Phalippou, J., Corriu, R.J.P., Leclercq, D., Vioux, A.: J. Non-Cryst. Solids113, 21 (1989)
Harp, G.R., Zhi-Lan Han, Tonner, B.P.: Phys. Scr. T31, 23 (1990)
Aoto, N., Ikawa, E., Endo, N., Kurogi, Y.: Surf. Sci.,234, 121 (1990)
Brodsky, M.H., Title, R.S.: Phys. Rev. Lett.23, 581 (1969)
Sufi Zafar, Schiff, E.A.: Phys. Rev. Lett.66, 1493 (1991)
Biswas, R., Wang, C.Z., Chan, C.T., Ho, K.M., Soukoulis, C.M.: Phys. Rev. Lett.63, 1491 (1989)
Pantelides, S.T.: Phys. Rev. Lett.23, 2979 (1986)
Connerade, J.P.: In: Fundamental processes of atomic dynamics, Briggs, J.S., Kleinpoppen, H., Lutz, H.O. (eds.): NATO Series B, vol. 181, p. 573, Fig. 5. New York: Plenum Press 1988
Dehmer, J.L., Dill, D., Parr, A.C.: In: Fundamental processes of atomic dynamics, Briggs, J.S., Kleinpoppen, H., Lutz, H.O. (eds.): NATO Series B, vol. 181, p. 541. New York: Plenum Press 1988
Giant resonances in atoms, molecules and solids, NATO Advanced Study Institute, series B, vol. 151, Connerade, J.P., Esteva, J.M., Karnatak, R.C. (eds.). New York: Plenum Press: 1987
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Flank, A.M., Karnatak, R.C., Blancard, C. et al. Probing matrix isolated SiO molecular clusters by X-ray absorption spectroscopy. Z Phys D - Atoms, Molecules and Clusters 21, 357–366 (1991). https://doi.org/10.1007/BF01438409
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DOI: https://doi.org/10.1007/BF01438409