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The synthesis of liquid crystalline lanthanide complexes and their magnetic birefringence

  • General and Inorganic Chemistry
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Russian Chemical Bulletin Aims and scope

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Abstract

Liquid crystalline complexes of the type [ML(LH)2](NO3)2, where LH=C7H15O-C6H3(OH)CH=N-C18H37 and M=Gd, Dy, and La, have been obtained. All of them exhibit the SA phase and have high magnetic birefringence constants due to the association of the complexes in solution. In the case of the dysprosium derivative, the effect is much stronger (four orders of magnitude greater than the usual value) because of the high magnetic anisotropy of the particles of the complex.

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Authors and Affiliations

  1. E. K. Zavoysky Kazan' Institute of Physics and Technology, Kazan' Scientific Center of the Russian Academy of Sciences, 10 ul. Sibirskii Trakt, 420029, Kazan', Russian Federation

    Yu. G. Galyametdinov, G. I. Ivanova & A. V. Prosvirin

  2. Kazan' State Technological University, 68 ul. K. Marksa, 420015, Kazan', Russian Federation

    O. Kadkin

Authors
  1. Yu. G. Galyametdinov
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  2. G. I. Ivanova
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  3. A. V. Prosvirin
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  4. O. Kadkin
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1003–1005, June, 1994.

The authors are grateful to Prof. S. G. Vul'fson for helpful advice and discussions.

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Galyametdinov, Y.G., Ivanova, G.I., Prosvirin, A.V. et al. The synthesis of liquid crystalline lanthanide complexes and their magnetic birefringence. Russ Chem Bull 43, 938–940 (1994). https://doi.org/10.1007/BF01558051

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  • DOI: https://doi.org/10.1007/BF01558051

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