Abstract
Mathematical considerations are used to show that the existence of an isokinetic point does not always indicate the kinetic compensation effect as a result of physicochemical reasons. The correlation of the Arrhenius parameters is given for both the inappropriate kinetic model function and the working temperature interval.
References
J. šesták, Thermophysical Properties of Solids, Elsevier, Amsterdam 1984.
A. I. Lesnikovich and S. V. Levchik, J. Thermal Anal., 20 (1985) 237; 677.
G. Pokol and G. Várhegyi, CRC Crit. Rev. Anal. Chem., 19 (1988) 65.
J. šesták, in H. G. Wiedeman (ed.), Thermal Analysis (Proc. 6th ICTA), Birkhauser Verlag, Stuttgart 1980, p. 29.
J. šesták, J. Thermal Anal., 32 (1987) 325.
N. Koga and J. šesták, Thermochim. Acta, in press.
N. Koga and H. Tanaka, J. Thermal Anal., submitted.
J. M. Criado and M. Gonzalez, Thermochim. Acta, 46 (1981) 201.
J. M. Criado, D. Dollimore and G. R. Heal, Thermochim. Acta, 54 (1982) 159.
J. M. Criado, M. Gonzalez, A. Ortega and C. Real, J. Thermal Anal., 29 (1984) 243.
J. M. Criado and A. Ortega, J. Thermal Anal., 29 (1984) 1075; 1225.
S. V. Vyazovkin and A. I. Lesnikovich, Thermochim. Acta, 165 (1990) 11.
K. N. Somasekharan and V. Kalpagam, Thermochim. Acta, 107 (1986) 379 and J. Thermal Anal., 32 (1987) 1471.
J. Málek, Thermochim. Acta, 138 (1989) 337.
N. Koga, J. šesták and J. Málek, Thermochim. Acta, submitted.
R. K. Agraval, J. Thermal Anal., 31 (1986) 73; 34 (1988) 1141; 35 (1989) 909.
N. Koga and H. Tanaka, Thermochim. Acta, submitted
B. N. Achar, G. W. Brindley and J. H. Sharp, Proc. Int. Clay. Conf. 1, Jerusalem 1966, p. 67.
H. L. Friedman, J. Polym. Sci., Part C, 6 (1964) 183.
T. Ozawa, Bull. Chem. Soc. Jpn., 38 (1965) 1881.
H. E. Kissinger, Anal. Chem., 29 (1957) 1702.
J. H. Flynn, in B. Pacewska and J. Pysiak (eds.), Proc. 5th Polish Conf. on TA, Plock 1989, p. 3; J. Thermal Anal., in press; in I. R. Harrison (ed.), Proc. 19th NATAS, Vol. II, Boston 1990, p. 389.
H. Tanaka and N. Koga, J. Thermal Anal, 32 (1987) 1521; 34 (1988) 685.
N. Koga and H. Tanaka, J. Thermal Anal., 34 (1988) 177.
N. Koga and H. Tanaka, Thermochim. Acta, 135 (1988) 79.
J. H. Flynn, J. Thermal Anal., 34 (1988) 367.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Koga, N., šesták, J. Further aspects of the kinetic compensation effect. Journal of Thermal Analysis 37, 1103–1108 (1991). https://doi.org/10.1007/BF01932804
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01932804