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Mercury from combustion sources: A review of the chemical species emitted and their transport in the atmosphere

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Abstract

Different species of mercury have different physical/chemical properties and thus behave quite differently in air pollution control equipment and in the atmosphere. In general, emissions of mercury from coal combustion sources are approximately 20–50% elemental mercury (Hg°) and 50–80% divalent mercury (Hg(II)), which may be predominantly HgCl2. Emissions of mercury from waste incinerators are approximately 10–20% Hg° and 75–85% Hg(II). The partitioning of mercury in flue gas between the elemental and divalent forms may be dependent on the concentration of particulate carbon, HCl and other pollutants in the stack emissions. The emission of mercury from combustion facilities depends on the species in the exhaust stream and the type of air pollution control equipment used at the source. Air pollution control equipment for mercury removal at combustion facilities includes activated carbon injection, sodium sulfide infection and wet lime/limestone flue gas desulfurization.

While Hg(II) is water-soluble and may be removed from the atmosphere by wet and dry deposition close to combustion sources, the combination of a high vapor pressure and low water-solubility facilitate the long-range transport of Hg° in the atmosphere. Background mercury in the atmosphere is predominantly Hg°. Elemental mercury is eventually removed from the atmosphere by dry deposition onto surfaces and by wet deposition after oxidation to water-soluble, divalent mercury.

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References

  • Ahmed, R., May, K. and Stoeppler, M.: 1987,Sci. Tot. Environ. 60, 249.

    Google Scholar 

  • Ames, M., Olmez, I., Meier, S. and Galvin, P.: (1993, July), ‘A Methodology for Determining Vapor Phase Mercury by Instrumental Neutron Activation Analysis,’ presented at the2nd Internat. Conf. on Managing Hazardous Air Pollutants, sponsored by the Electric Power Research Institute, Washington, DC.

  • Bergstrom, J. G. T.: 1986,Waste Manage. Res. 4(1), 57.

    Google Scholar 

  • Bloom, N. S. and Watras, C. J.: 1989, ‘Observations of Methylmercury in Precipitation,’Sci. Tot. Environ. 87/88, 199.

    Google Scholar 

  • Bloom, N. S. and Fitzgerald, W. F.: 1988,Anal. Chim. Acta 208, 151.

    Google Scholar 

  • Brosset, C. and Lord, E.: 1991,Water, Air, and Soil Pollut. 56, 493.

    Google Scholar 

  • Brosset, C.: 1987,Water, Air, and Soil Pollut. 34(2), 145.

    Google Scholar 

  • Brosset, C.: 1983.Water Sci. Technol. 15(12), 59.

    Google Scholar 

  • Brunner, P. H. and Monch, H.: 1986,Waste Manage. Res. 4(1), 105.

    Google Scholar 

  • Carpi, A., Ditz, D. W. and Weinstein, L. H.: 1994,J. Air Waste Manage. Assoc. 44(5), 669.

    Google Scholar 

  • Clean Air Act Amendments of 1990, 42 U.S.C. § 7429 (Supp. III, 1991).

  • Chu, P. and Porcella, D. B.: 1995,Water, Air, and Soil Pollut. 80, 135.

    Google Scholar 

  • Chu, P., Nott, B. and Chow, W.: 1993, July, ‘Results and Issues from the Pisces Field Tests,’ presented at2nd Internat. Conf. on Managing Hazardous Air Pollutants, sponsored by the Electric Power Research Institute, Washington, DC.

  • CRC: 1982,Handbook of Chemistry and Physics, 63rd edition, CRC, Boca Raton, FL.

    Google Scholar 

  • DeMora, S. J., Bibby, D. M. and Patterson, J. E.: 1991,Environ. Technol. 12(10), 943.

    Google Scholar 

  • DeVito, M. S., Tumati, P. R., Carlson, R. J. and Bloom, N.: 1993, July, ‘Sampling and Analysis of Mercury in Combustion Flue Gas,’ presented at2nd Internat. Conf. on Managing Hazardous Air Pollutants, sponsored by the Electric Power Research Institute, Washinton, DC.

  • Felsvang, K., Gleiser, R., Juip, G. and Nielsen, K. K.: 1993, July, ‘Air Toxics Control by Spray Dryer Absorption Systems,’ presented at2nd Internat. Conf. on Managing Hazardous Air Pollutants, sponsored by the Electfic Power Research Institute, Washington, DC.

  • Fitzgerald, W.F., Mason, R. P. and Vandal, G. M.: 1991,Water, Air, and Soil Pollut. 56, 745.

    Google Scholar 

  • Gilmour, C. C. and Henry, E. A.: 1991,Environ. Pollut. 71(2–4), 131.

    PubMed  Google Scholar 

  • Glass, G. E., Sorensen, J. A., Schmidt, K. W. and Rapp, G. R.: 1990,Environ. Sci. Technol. 24(7), 1059.

    Google Scholar 

  • Guest, T. L. and Knizek, O.: 1991, June, ‘Mercury Control at Burnaby's Municipal Waste Incinerator,’ presented at8th Meeting Air Waste Manage. Assoc., Vancouver, B.C.

  • Greenberg, A., Wojtenko, I., Chen, H., Krivanek, S., Butler, J. P., Held, J., Weis, P. and Reiss, N. M.: 1992, May, ‘Mercury in Air and Rainwater in the Vicinity of a Municipal Resource Recovery Facility in Northwestern New Jersey,’ presented at theMeasurement of Toxic and Related Air Pollutants, Air Waste Manage. Assoc., Durham, NC.

    Google Scholar 

  • Hall, B.: 1995,Water, Air, and Soil Pollut. 80, 301.

    Google Scholar 

  • Hall, B., Schager, P. and Lindqvist, O.: 1991,Water, Air, and Soil Pollut. 56, 3.

    Google Scholar 

  • Hall, B., Lindqvist, O. and Ljungstrom, E.: 1990,Environ. Sci. Technol. 24(1), 108.

    Google Scholar 

  • Iverfeldt, Å: 1991a,Water, Air, and Soil Pollut. 56, 251.

    Google Scholar 

  • Iverfeldt, Å: 1991b,Water, Air, and Soil Pollut. 56, 553.

    Google Scholar 

  • Jozewicz, W., Krishnan, S. V. and Gullett, B. K.: 1993, July, ‘Bench-Scale Investigation of Mechanisms of Elemental Mercury Capture by Activated Carbon’, presented at the2nd Internat. Conf. on Managing Haz. Air Pollut., sponsored by the Electric Power Research Institute, Washington, DC.

  • Keeler, G., Glinsorn, G. and Pirrone, N.: 1995,Water, Air, and Soil Pollut. 80, 159.

    Google Scholar 

  • Krivanek, C. S.: 1993, March 30 — April 2, ‘Mercury Control Technologies for MWC's; The Unanswered Questions’, presented at the3rd Internat. Conf. on Mun. Waste Combust., sponsored by the Air Waste Manage. Assoc., Williamsburg, VA.

  • Lee, Y-H. and Iverfeldt, A.: 1991,Water, Air, and Soil Pollut. 56, 309.

    Google Scholar 

  • Lindberg, S. E.: 1987, ‘Emission and Deposition of Atmospheric Mercury Vapor,’ in Hutchinson, T. C. and Meema, K. M. (eds.),Lead, Mercury, Cadmium and Arsenic in the Environment, Wiley & Sons, Chichester, pp. 89–106.

    Google Scholar 

  • Lindqvist, O., Johansson, K., Aastrup, M., Andersson, A., Bringmark, L., Hovsenius, G., Håkanson, L., Iverfeldt, Å., Meili, M. and Timm, B.: 1991,Water, Air, and Soil Pollut. 55, 1.

    Google Scholar 

  • Lindqvist, O.: 1986,Waste Manage. Res. 4(1), 35.

    Google Scholar 

  • Lindqvist, O. and Rodhe, H.: 1985,Tellus 37B(3), 136.

    Google Scholar 

  • Maserti, B. E. and Ferrara, R.: 1991,Water, Air, and Soil Pollut. 56, 15.

    Google Scholar 

  • Meij, R.: 1991,Waster, Air, and Soil Pollut. 56, 21.

    Google Scholar 

  • Miller, S. J., Laudal, D. L., Chang, R. and Bergman, P.D.: 1994, ‘Laboratory-Scale Investigations of Sorbents for Mercury Control,’ presented at87th Meeting Air Waste Manage. Assoc., Cincinnati, June 19–24.

  • Munthe, J.: 1992,Atmos. Environ. 26A(8), 1461.

    Google Scholar 

  • Munthe, J., Xiao, Z. F. and Lindqvist, O.: 1991,Water, Air, and Soil Pollut. 56, 621.

    Google Scholar 

  • Nater, E. A. and Grigal, D. F.: 1992,Nature 358, 139.

    Google Scholar 

  • Nriagu, J. O. (ed.): 1979,The Biogeochemistry of Mercury in the Environment, Elsevier/North-Holland Biomedical, Amsterdam.

    Google Scholar 

  • NJ DEPE: 1993,Task Force on Mercury Emissions Standard Setting: Final Report on Municipal Solid Waste, Technical and Regulatory Issues, Vol. III, New Jersey Department of Environmental Protection and Energy.

  • Otani, Y., Emi, H., Kanaoka, C. and Matsui, S.: 1984,Environ. Sci. Technol. 18(10), 793.

    Google Scholar 

  • Pacyna, J. M. and Munch, J.: 1991,Water, Air, and Soil Pollut. 56, 51.

    Google Scholar 

  • Prestbo, E. M. and Bloom, N. S.: 1995,Water, Air, and Soil Pollut. 80, 145.

    Google Scholar 

  • Reimann, D. O.: 1986,Waste Manage. Res. 4(1), 45.

    Google Scholar 

  • Schroeder, W. H., Yarwood, G. and Niki, H.: 1991,Water, Air, and Soil Pollut. 56, 653.

    Google Scholar 

  • Schroeder, W. H. and Jackson, R. A.: 1987,Chemosphere 16(1), 183.

    Google Scholar 

  • Schroeder, W. H., and Jackson, R. A.: 1985,Intern. J. Eniron. Anal. Chem. 22, 1.

    Google Scholar 

  • Seigneur, C., Wrobel, J. and Constantinou, E.: 1994,Environ. Sci. Technol. 28(9), 1589.

    Google Scholar 

  • Shendrikar, A. D. and Ensor, D. S.: 1986,Waste Manage. Res. 4(1), 75.

    Google Scholar 

  • Slemr, F., Schuster, G. and Seiler, W.: 1985,J. Atmos. Chem. 3, 407.

    Google Scholar 

  • Stratton, W. J. and Lindberg, S. E.: 1995,Water, Air, and Soil Pollut. 80, 1269.

    Google Scholar 

  • U.S. Environmental Protection Agency (1993, September)Emission Test Report, Field Test of Carbon Injection for Mercury Control, Camden County Municipal Waste Combustor, EPA-600/R-93-181, Office of Research and Development, Washington, DC.

    Google Scholar 

  • U.S. Environmental Protection Agency (1992, September)Emission Test Report. OMSS Field Test on Carbon Injection for Mercury Control, EPA-600/R-92-192, Office of Research and Development, Washington, DC.

    Google Scholar 

  • U.S. Environmental Protection Agency (1990, September)Summary of Information Related to Mercury Emission Rates and Control Technologies Applied to Municipal Waste Combustors, Office of Air Quality Planning and Standards, Research Triangle Park, NC.

    Google Scholar 

  • U.S. Environmental Protection Agency (1984)Mercury Health Effects Update: Health Issue Assessment, EPA-600/8-84-019F, Environmental Criteria and Assessment Office, Research Triangle Park, NC.

    Google Scholar 

  • Vogg, H., Braun, H., Metzger, M. and Schneider, J.: 1986,Waste Manage. Res. 4(1), 65.

    Google Scholar 

  • WHO (1991)Environmental Health Criteria 118: Inorganic Mercury, World Health Organization, Geneva.

    Google Scholar 

  • WHO (1990)Environmental Health Criteria 101: Methylmercury, World Health Organization, Geneva.

    Google Scholar 

  • Xiao, Z. F., Munthe, J. and Lindqvist, O.: 1991,Water, Air, and Soil Pollut. 56, 141.

    Google Scholar 

Download references

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  1. Field of Environmental Toxicology, Boyce Thompson Institute at Cornell University, Ithaca, NY, USA

    Anthony Carpi

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Carpi, A. Mercury from combustion sources: A review of the chemical species emitted and their transport in the atmosphere. Water Air Soil Pollut 98, 241–254 (1997). https://doi.org/10.1007/BF02047037

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  • DOI: https://doi.org/10.1007/BF02047037

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