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Catalytic properties of sodium-containing silica gel in n-heptane decomposition

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Abstract

n-Heptane decomposition reactions on silica catalysts containing various amounts of sodium ions were studied. Ethylene, methane and propylene as well as unbrached α-olefins were the main reaction products. The comparison of the experimental and theoretical results suggests a free-radical reaction mechanism.

Abstract

Были исследованы реакции разложения н-гептана на катализаторе двуокиси кремния, содержащем различные количества ионов натрия. Основными продуктами были этилен, метан и пропилен, а также неразветвленные α-олефины. Сравнение экспериментальных данных с теоретическими указывает на свободно-радикальный механизм реакции.

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Authors and Affiliations

  1. Institute of Organic Chemistry and Technology, Technical University (Politechnika), Warsaw, Poland

    S. Malinowski, T. Woźniewski & E. Fedoryńska

Authors
  1. S. Malinowski
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  2. T. Woźniewski
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  3. E. Fedoryńska
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Malinowski, S., Woźniewski, T. & Fedoryńska, E. Catalytic properties of sodium-containing silica gel in n-heptane decomposition. React Kinet Catal Lett 7, 219–224 (1977). https://doi.org/10.1007/BF02061842

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  • DOI: https://doi.org/10.1007/BF02061842

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