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Peculiarities of relaxation self-oscillations in catalytic reactions (“splashes”, “false steady states”)

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Abstract

An interpretation is given of “splashes” — sharp long-living variations in reaction parameters, registered in a number of kinetic experiments. The model of the simplest catalytic mechanism providing relaxation self-oscillations is used.

Abstract

В работе дается интерпретация “всплесков” — резких кратковременных изменений характеристик реакции, фиксируе-мых в ряде кинетических экспериментов. В качестве моде-ли используется модель простейшего каталитического механизма, обеспечивающего релаксационные колебания.

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Authors and Affiliations

  1. Institute of Mathematics, 630090, Novosibirsk, USSR

    V. M. Goldshtein

  2. Institute of Catalysis, 630090, Novosibirsk, USSR

    V. F. Kim & G. S. Yablonskii

Authors
  1. V. M. Goldshtein
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  2. V. F. Kim
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  3. G. S. Yablonskii
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Goldshtein, V.M., Kim, V.F. & Yablonskii, G.S. Peculiarities of relaxation self-oscillations in catalytic reactions (“splashes”, “false steady states”). React Kinet Catal Lett 34, 361–366 (1987). https://doi.org/10.1007/BF02068031

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  • DOI: https://doi.org/10.1007/BF02068031

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