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Epoxidation of cyclohexene with tert-butyl hydroperoxide catalyzed by polymer anchored molybdenum complexes

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Abstract

Catalytic activity of molybdenum hexacarbonyl anchored on various polymers was investigated for the epoxidation of cyclohexene with tert-butyl hydroperoxide. The activity was increased by anchoring on the polymer. The catalyst on polystyrene showed much higher activity than Mo(CO)6 used under homogeneous conditions.

Abstract

Каталитическую активность гексакарбонила молибдена, привитого к различным полимерам, тестировали в зпоксидировании циклогексена трет.—бутильным гидропероксидом. Активность увеличивается со степенью прививки к полимеру. Катализатор на полстироле обладает гораздо большей активнос]qtью, чем Mo(CO)6, используемый в гогенных условиях.

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Author notes

  1. Motonobu Goto

    Present address: Department of Applied Chemistry, Kumamoto University, 860, Kumamoto, Japan

Authors and Affiliations

  1. Department of Chemical Engineering, Nagoya University, 464-01, Nagoya, Japan

    Shigeo Goto

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  1. Motonobu Goto
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  2. Shigeo Goto
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Goto, M., Goto, S. Epoxidation of cyclohexene with tert-butyl hydroperoxide catalyzed by polymer anchored molybdenum complexes. React Kinet Catal Lett 39, 267–271 (1989). https://doi.org/10.1007/BF02071338

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  • DOI: https://doi.org/10.1007/BF02071338

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