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Cyclohexane dehydrogenation over Pt-Dy/Al2O3 catalysts

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Abstract

The conversion of cyclohexane dehydrogenation over Pt−Dy/Al2O3 has been studied with a pulsed microcatalytic reactor. Two interesting experiments utilizing CS2 and thiophene poisoning Pt/Al2O3 and Pt−Dy/Al2O3 for cyclohexane dehydrogenation are shown and the reaction mechanism is described. The kinetic parameters of cyclohexane dehydrogenation have been calculated. Correlation of the catalytic behavior with the properties of active sites is also discussed.

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Author notes

  1. Cheng Shibiao

    Present address: Department of Chemistry, School of Chemical Engineering, Dalian University of Technology, 116012, Dalian, China

Authors and Affiliations

  1. Department of Chemistry, Nanchang University, Nanjing-dong road 17, 330047, Nanchang, China

    Cheng Shibiao, Li Fengyi, Luo Laitai & Zhen Zhaoping

Authors
  1. Cheng Shibiao
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  2. Li Fengyi
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  3. Luo Laitai
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  4. Zhen Zhaoping
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Shibiao, C., Fengyi, L., Laitai, L. et al. Cyclohexane dehydrogenation over Pt-Dy/Al2O3 catalysts. React Kinet Catal Lett 55, 391–397 (1995). https://doi.org/10.1007/BF02073075

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  • DOI: https://doi.org/10.1007/BF02073075

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